查询词典 aromatic compounds

The results of the present research are as follows, The correlation between physico-chemical properties of organic compounds and their competitive power was studied, and it was indicated that organic compounds preferable to form H-bonding with organic matter of sorbents have stronger competitive power; Sorption behaviors of ionizable organic compounds in different species and their competitive power were examined, and the results showed that phenols and carbonxylic acids with benzyl circle have much stronger competitive power in molecular species than in ionized species, because negative charges of anionic forms can depressed their adsorption on the surface of the sediment; in contrast, organic bases such as aniline and p-chloroaniline show weaker competitive power in molecular species than in ionized species, and this is because both species of the organic bases could adsorb strongly onto the sediment; there is a correlation between competitive power of organic pollutants in multi-solute systems and their sorption isotherm nonlinearity in single-solute systems, and organic compounds whose sorption isotherms is linear in single-solute systems hardly have competitive power in multi-solute systems; Competitive sorption effects in more than two-solutes systems was studied, and it was exhibited that mixture of two cosolutes each of which could suppress sorption of nominal solute onto the sediment had synergistically competitive sorption effect on the nominal solute; A method about incorporating sorption/desorption of organic pollutants into river water quality model was developed, and discussion about degree of sorption/desorption effect on model prediction for different organic compounds was made, which will provide theoretical basis and practical processes for setting up more accurate water quality model.

论文主要取得了以下研究成果。(1)有机化合物的吸附竞争能力与其物化性质具有相关性，易与沉积物有机质形成氢键的化合物其竞争能力也比较强；(2)可离子化有机化合物的吸附竞争能力与其存在形态有关。酚类、含苯环的羧酸类化合物，其离子态的吸附竞争能力远小于分子态，其机理为有机酸阴离子所带的负电荷抑制了表面吸附能力，主要发生分配作用；而苯胺类化合物，其离子态和分子态都表现出显著的竞争能力，而且离子态的竞争能力略强于分子态，原因在于有机碱阳离子所带的正电荷促进了其表面吸附能力；有机化合物竞争能力的强弱与其单组分吸附等温线的非线性程度具有一定的相关性，吸附等温线近似为线性的化合物没有或只具有微弱的竞争能力；(3)对目标有机化合物的吸附具有竞争效应的有机化合物混合后，将对目标有机化合物的吸附产生协同竞争效应；(4)以京杭运河为例，率先提出了将有机污染物的吸附／脱附作用及水文水力参数耦合到水质模型中的方法，并讨论了吸附／脱附作用对不同有机污染物预测模型的影响，为建立更准确的水质模型及进行更客观的风险和生态评估提供了参考依据。

Gas chromatography and mass spectrometry technique were employed to analyze the ginger oleoresin. This analysis resulted in the detection of 3 hitherto unknown natural compounds, 24 compounds previously reported as pungent compounds and 50 volatile compounds from ginger. The volatile compounds were mainly α-zingiberene (22.29%),β-sesquiphellandrene (8.58%),α-farnesene (3.93%),β-bisabolene (3.87%),α-curcumene (2.63%), which were mostly consisted of sesquiterpene hydrocarbons.

从姜油树脂中分析出77种化合物，其中挥发油成分50种，主要是α-姜烯(22.29%)、β-倍半水芹烯(8.58%)、α-法尼烯(3.93%)、β-没药烯(3.87%)和α-姜黄烯(2.63%)等倍半萜类化合物；姜辣素成分27种，主要成分为6-姜酚(9.38%)、6-姜烯酚(7.59%)和分析过程中由姜酚类或姜烯酚类化合物受热分解而形成的姜油酮(9.24%)。

The results showed that 42 compounds were identified from perianth at 5 stages, including 18 terpenoid compounds, 7 ester compounds, 4 alcohol compounds, 1 ketone compound, 11 alkanes compounds and 1 unknown compound.

结果表明，5个时期的含笑花被片共鉴定出42种化学成分：萜类化合物18种、酯类化合物7种、醇类化合物4种、酮类化合物1种、烷烃类物质11种和未知物1种。

As a result of aromatization of organic matter during the thermal cracking of original bitumen into gas,the aromatic hydrocarbons in the bitumen are characterized by abnormally abundant tetra-and penta-cyclic compounds,and predominated by parent aromatic compounds without alkyl chain,such as fluoranthene,pyrene,chrysene, benzofluoranthene etc.

沥青的芳烃组成独特，富含四、五环芳烃化合物，且以萤蒽、芘、和苯并萤蒽等无烷基取代的母体芳烃化合物为主，反映出沥青裂解成气过程中的有机质芳构化作用。

The condensation of aromatic aldehydes with active methylene compounds like malononitrile, cyanoacetamide and ethyl cyanoacetate has been found to proceed very efficiently at room temperature giving excellent yields, but the condensation of heteroaromatic,α,β-unsaturated and aliphatic aldehydes with active methylene compounds proceeded smoothly in 50~65℃ with good yields and the reactions of aromatic, aliphatic ketones as well as p-phthalaldehyde with malononitrile also proceeded in 75~85℃ with moderate yields.

芳香醛与活泼亚甲基化合物如丙二腈、氰基乙酸乙酯、氰基乙酰胺的缩合在室温下即能顺利进行，获得了很高的收率；而对于杂环芳醛、α，β-不饱和的醛以及脂肪醛与活泼亚甲基化合物的缩合，需在50~65℃下进行，也取得了很高的收率；对于脂肪酮、芳香酮以及二元醛与丙二腈的缩合在75~85℃下也能顺利地进行，获得中等以上的收率。

A catalyst composition for the polymerization of propylene comprising one or more Ziegler-Natta procatalyst compositions comprising one or more transition metal compounds and one or more esters of aromatic dicarboxylic acid internal electron donors; one or more aluminum containing cocatalysts; and a mixture of two or more different selectivity control agents, said SCA mixture comprising from 1 to 99 percent of one or more esters of one or more aromatic monocarboxylic acids or substituted derivatives thereof, and from 99 to 1 percent of one or more alkoxysilane compounds.

一种用于丙烯聚合的催化剂组合物，包括：一种或多种齐格勒-纳塔主催化剂组合物，该齐格勒-纳塔主催化剂组合物包括一种或多种过渡金属化合物和一种或多种芳族二羧酸酯内部电子给体；一种或多种包含铝的辅催化剂；和两种或更多种不同的选择性控制剂的混合物，所述SCA混合物包括1到99％的一种或多种芳族单羧酸的一种或多种酯或其取代衍生物、和99到1％的一种或多种烷氧基硅烷化合物。

Halogenated aromatic compounds with great q〓(the most negative net atomic charges on an atom of the molecule), ENC (electron-nuclear attraction energy of the one-center term for the carbon atoms of the weakest carbon-halogen bond), qc (thenet atomic charges on the carbon atom of the weakest carbon-halogen bond) and E〓 tend to be reductively dehalogenated slow, while halogenated aromatic compounds with high values of △E (the difference of front-line orbital energy), EEC (electron-electron repulsion energy of the one-center term for the carbon atoms of the weakest carbon-halogen bond), Mw, q〓 and α tend to be reductively dehalogenated fast.

卤代芳烃化合物的整个分子的最负的原子净电荷，键序最小的碳卤键中碳原子的单中心项电子-核吸引能，该碳-卤键上碳原子的净电荷和E〓与该卤代芳烃化合物还原脱卤的速率常数负相关；而前线轨道间隙能，键序最小的碳卤键中碳原子的单中心项电子-电子推斥能，Mw，q〓和α与该卤代芳烃化合物还原脱卤的速率常数正相关。

Five types of compounds were synthesized via modification of the leading compounds, Mannich bases of cyclopentanones. Among the target compounds, one type was aromatic amine derivatives of a leading compound, three were Mannich bases of a - benzylidene cyclopentanone, the fifth was a Mannich base of a - benzyl cyclopentanone.

以具有抗炎活性的环戊酮Mannich碱为先导化合物进行结构改造，设计合成了一类已知化合物的芳胺Mannich碱衍生物，三类α-苯亚甲基环戊酮Mannich碱类化合物，一类α-苄基环戊酮Mannich碱类化合物。22个目标化合物的结构经核磁共振氢谱、红外光谱和质谱检测确证。

Additionally, 75 volatile chemical constituents have been identified from the petroleum ether extracted part by capillary GC-MS, and the relative percentages of them are determined by GC method. The result showed that the volatile constituents of Musella lasiocarpa mainly includes advanced alkane, aliphatic acid and ester, aldehyde, ketone, aromatic and its heterocyclic compounds. With the compounds that have been isolated and identified from Musella lasiocarpa, the biogenensis pathway of new compound MT-3 is approached. Furthermore, the bacteriostasis of the 6 compounds to Escherichia coil, Pseudomonas aerusinosa, Bacillus megaterium, Sarcina lutea and Bacillus subtilic are determined by flat dilution method.

此外，从其石油醚萃取部分用毛细管色谱法分析鉴定出75种挥发性化学成分，并测定了各组分的相对百分含量，结果表明，地涌金莲挥发性化学成分以高级烷烃、高级脂肪酸酯及醛、酮、芳香和芳香杂环化合物为主；根据从地涌金莲中鉴出和分离得到的化合物，探讨了新结构化合物MT-3的生源代谢途径；采用平板稀释法测定了地涌金莲中六种化学成分对大肠杆菌、绿脓杆菌、巨大芽孢杆菌、藤黄八叠球菌和枯草芽孢杆菌的抑菌作用。

The application, proposed hydrotalcite-like compounds as a new type of environmentally friendly solid catalysts in the aldol condensation, nitrile hydrolysis, epoxide ring-opening reaction of the oxidation of aromatic compounds, alcohols oxidation, reduction of nitro compounds, and many other important reactions in organic synthesis has an important application potential, and with little pollution compared to conventional catalysts, easy separation of advantages of high reactivity.

叙述了水滑石类化合物作为固体酸碱催化剂、氧化还原反应催化剂、催化剂载体等方面的应用情况，提出了水滑石类化合物作为一类新型的环境友好的固体催化剂，在醇醛缩合、腈类水解、环氧化物的开环反应、芳烃类化合物的氧化、醇类氧化、硝基化合物的还原等许多重要的有机合成反应具有重要的应用前景，并且与传统催化剂相比具有污染小、易分离、反应活性高等优点。

There had been a moment during the breakfast meeting, though, after the backslapping and the small talk and when all of us were seated, with Vice President Cheney eating his eggs Benedict impassively and Karl Rove at the far end of the table discreetly checking his BlackBerry, that I witnessed a different side of the man.

那次早餐会期间，在表示过关心和寒暄以后，我们所有人坐了下来，我注意观察了一下，副总统切尼面无表情地吃着班尼迪克蛋（Eggs benedict，源自美国，以英式松饼、火腿、水煮蛋以及荷兰酱组合而成），卡尔。罗夫在餐桌的远端谨慎地经常查看他的黑莓手机，我目睹了他所不为人知的一面。

Talk Undelete failed; someone else may have undeleted the page first.

Talk 无法删除选定的页面或图像（它可能已经被其他人删除了）。