查询词典 amine acid

We have used GC to follow up the formation of epoxy acid and established the acidify condition; we have done series of parallel experiments to better the pivotal condensation reaction between acid and amine; In the cyclization step, we use cheap and available reagent-Lithium amide , rather than expensive LiHMDS, to proceed the reaction; and at last, we introduced green reagent-ozone to clear the phenyl group of nitrogen to avoid using heavy metal reagent-CAN. The total yield for this method is 29.8%.

通过GC监测，确定环氧酸的最佳酸化条件；对关键的酸和胺的缩合步骤，平行试验了多种条件；在环合一步，用价廉易得的氨基锂及催化量的HMDS代替昂贵的LiHMDS进行反应；氮上苯基的脱除采用臭氧，避免了重金属试剂-硝酸铈铵的使用，总收率为29.8％。

The result was showed that the optimal process conditions were presented as follows: molar ratio of methyl glucose amine to oleic acid 2.5, reaction time 8h, reaction temperature 90℃, and the catalyst dosage 1.5% to the oleic acid reaction.

结果表明，最佳工艺条件为：甲基葡萄糖酰胺和油酸的摩尔比为2.5，反应时间为8 h，反应温度为90℃，催化剂用量占油酸用量的摩尔分数为1.5%。

Our country ethylene diamine mainly uses in producing the agricultural chemicals (woods manganese zinc, dithane Z-78, generation of woods amine and pesticide, weed killer, disinfectant), the surface active agent (lives geminate stearic acid amide, alkyl imidazole lin, double amide, with oxirane, epoxypropane synthesizes non-ionic surface active agent), the epoxy resin firming agent (polyamide resins, epoxy firming agent, hydroxyethyl ethylene diamine and so on), the wash assistant (ethylene diamine four ethanoic acid and sodium salt series chelating agents), medicine raw material (aminophylline, washes must be peaceful, nose eye only, deinsectization spirit and so on), water treatment medicinal preparation (ethylene diamine four methylene phosphonates, second grade trunk base ethylidene two phosphine acids), corrosion inhibitor dye fixing agent, photography materialFixing bath and oil dope and so on.

我国乙二胺主要用于生产农药（森锰锌、代森锌、代森胺及杀虫剂、除草剂、杀菌剂），表面活性剂（生成双硬脂酸酰胺，烷基咪唑啉、双酰胺，与环氧乙烷，环氧丙烷合成非离子表面活性剂），环氧树脂固化剂（聚酰胺树脂，环氧固化剂，羟乙基乙二胺等），洗涤助剂（乙二胺四乙酸及其钠盐系列螯合剂），医药原料（氨茶碱，洗必泰，鼻眼净，灭虫灵等），水处理剂（乙二胺四甲叉膦酸盐，乙脒基乙叉二膦酸），缓蚀剂染料固色剂，照相材料定影液及润滑油添加剂等。

Main products include: 1,3-dimethyl-2-imidazolone, also named dimethyl-ethenylurea, 1,3-Dimethyl-2-imidazolone、1,3- Dimethyl-3,4,5,6- four hydrogen-2-pyrimidone, 2-imid-azolidinone、methane acid amine,、pyridylmethanol、pyridylaldehyde、50% methane acid,etc series products.

公司主营：1，3-二甲基-2-咪唑啉酮，又称二甲基乙烯脲，1，3-Dimethyl-2-imidazolinone、1，3-二甲基-3，4，5，6-四氢-2-嘧啶酮、 2-咪唑啉酮、甲酸胺、吡啶甲醇、吡啶甲醛、50%甲酸等系列产品。

Main products include: 3-Dimethyl-2-imidazolidinone, also named dimethyl-ethenylurea, 3-Dimethyl-2-imidazolidinone、1,3- Dimethyl-3,4,5,6- four hydrogen-2-pyrimidone, 2-imid-azolidinone、methane acid amine,、pyridylmethanol、pyridylaldehyde、50% methane acid,etc series products.

公司主营：1，3-二甲基-2-咪唑啉酮，又称二甲基乙烯脲， 1， 3-Dimethyl-2-imidazolidinone、1，3-二甲基-3，4，5，6-四氢-2-嘧啶酮、 2-咪唑啉酮、甲酸胺、吡啶甲醇、吡啶甲醛、50%甲酸等系列产品。

The key steps involved Friedel-Crafts reaction of o-cresol and the Wittig reaction for construction the skeleton of amine moiety,at the same time, using the synthesis of E,(7S)-7-methoxytetradec-4-enoic acid in chapter 2,and Johnson-Clainsen rearrangement as a key step for construction the fatty acid part,the corresponding acid was prepared in 23%and 50%overall yield,respectively.

随后将手性不饱和脂肪酸和氨片段进行酰胺化反应构筑了malyngamide M的基本骨架，再将Z-烯氯转化为E-烯氯完成了目标分子的全合成，高立体选择性地构筑了末端烯氯结构，为制备其它含有类似烯氯结构的malyngamides探索出行之有效的合成路线。

The costs of abietic acid separating with A amine salt method and B amine salt method were 1/5 and 1/3 of cost separating with di-n-amylamine salt reported in the literature respectively.

同时研究了以酸异构化、高温异构化和微波辅助酸异构化松香制备枞酸含量较高的异构化松香的实验条件，以异构化松香为原料，采用多种方法分离提纯枞酸，得到最佳分离提纯条件。

One route was that the amino-groups on the silica gel were transformed to tertiary amines by Eschweiler-clarke reaction that amine-groups react with formaldehyde and methanoic acid to prepare tertiary amines; the silica gel intermediates with tertiary amine groups reacted with chorohydrocarbons to prepare insoluble silica gel quaternary ammonium salt bactericides. Another route was that the amino-groups on the silica gel reacted with excessive chlorohexadecane; the preparing intermediates were quaternized with iodomethane to obtain insoluble silica gel quaternary ammonium salt bactericides.

一条路线是根据埃施韦勒-克拉克(Eschweiler-clarke)胺甲基化反应，进行胺基叔胺化反应，制成带有叔胺官能团的硅胶中间体，此中间体上的叔胺与卤代烷反应生成杀菌活性官能团季铵盐，制成硅胶类水不溶性季铵盐杀菌剂；另一条路线是带有胺反应活性中心的硅胶与过量正氯代十六烷反应，得到的中间体再用碘甲烷季铵化，得到最终产品——水不溶性季铵盐杀菌剂。

A series of UV curable waterborne hyperbranched polyester s with different acid/amine terminal rate,which contained -OH?-COOH and methacrylic chain end groups,and were partly neutralized with thertiary amine,were synthesized from trimellitic anhydride,epichlorohydrin,glycidyl methacrylate and triethylamine.

以偏苯三酸酐、环氧氯丙烷、甲基丙烯酸缩水甘油酯、三乙胺合成了末端羧基与氨基不同比例的一系列可UV固化的高支化聚酯，研究了末端官能团对合成产物水溶性、粘度以及凝胶转化率的影响。

Two series of polyurethane acrylate grafted acrylic resins (Acr-g-TPU-PETA and Acr-gPPU-PETA) self-emulsifying systems are obtained by grafting -NCO group modified polyurethane acrylates with acrylic copolymer prepared from n-butyl acrylate, styrene,βhydroxyethyl methacrylate and acrylic acid The self-emulsifying systems showed Newtonian fluidity with viscosity closed to that of water, the solid contents were around 30% The T〓 of 15～4℃ for dried film before photocuring favored film formation at room temperature DSC and DMA results showed that PU-PETA is compatible with acrylic resin in the grafted resin The TG and dTG curves for Acr-g-PU-PETA samples were substantially different from the corresponding blends, and the brodened dTG peaks for photocured grafted resin suggest that there might be multiple interactions among chain segments The photocued film of the grafted resins self-emulsifying system exhibited good overall properties with polyurethane acrylate grafts ranging from 30% to 50%, and Acr-g-TPU-PETA series showed better properties than Acr-gPPU-PETA series The adhesion of the photocured film was 1～2 grade, impact strength was 50kg-cm and flexibility was 1mm The Shore hardness and the adhesion of the film decreased markedly if PETA was replaced by HEMA as photoactive group due to the lower C=C double bond content in the grafted resin The polyhydroxy amine-linked thioxanthones photoinitiators can be evenly dispersed in self-emulsifying system without color spot appearing in the dried film The films photocured with IV〓～IV〓 generally exhibited higher Shore hardness, gloss and solventresistance than that cured with Irgacure 2959 and did not induce the rusting of the iron substrate Pigmenting with titanium oxide had no effect on the photocuring The polyhydroxy amine-linked thioxanthone IV〓 and IV〓 can be new candidates for the formulation of titanium oxide pigmented photocurable water-borne coatings for their pale-yellow appearance and slight interference with the color of the coatings WB 4759 with high water-solubility coalesced and separated from the dried resin film, and even induced the rusting of iron substrate.

以丙烯酸丁酯，甲基丙烯酸-β-羟乙酯，丙烯酸及苯乙烯合成厂丙烯酸共聚树脂，并与含-NCO端基的聚氨酯丙烯酸酯接枝反应，经水性化后，得到两个系列（Acr-g-TPU-PETA和Acr-g-PPU-PETA）各5个不同配比的丙烯酸树脂接枝聚氨酯丙烯酸酯自乳化体系，粘度与水相近，为牛顿流体，固含量30％左右。光固化前干燥涂膜的玻璃化转变温度在-15℃～4℃之间，有利于室温下成膜。DSC及DMA谱表明两种树脂基本相容。Acr-g-PU-PETA的热失重行为明显不同于共混材料，接枝样dTG峰明显宽化，表明接枝样中链段之间的相互作刚有多重性，丙烯酸树脂与聚氨酯之间有一定的相容性。接枝树脂自乳化体系光固化涂层的综合性能以聚氨酯丙烯酸酯成分为50％～30％者相对较好，且以Acr-g-TPU-PETA系列更理想。光固化膜的附着力为1～2级，冲击强度为50kg·cm，柔软性多为1mm。以HEMA代替PETA作为接枝树脂的活性基团，碳—碳双键密度太低，光固化膜交联点太少，硬度和附着力均较差。多羟基胺连硫杂蒽酮光引发剂能均匀分散于树脂自乳化体系和接枝树脂干膜中，不出现色斑，光固化膜肖氏硬度一般高于以Irgacure 2959为光引发剂的光固化膜，光泽度及耐丁酮溶剂性能均有所提高，不会诱导铁基生锈，钛白着色对光固化结果几乎没有影响。本论文所合成的多羟基胺连硫杂蒽酮光引发剂IV〓与IV〓为浅黄色，对光固化涂层的颜色干扰较小，为配制钛白着色光固化水性涂料提供了新的光引发剂。水溶性太强的WB 4759在干膜中易聚结析出，且对所附着的铁基有诱导锈蚀作用。

We will see more and more activist government policies that distinguish economic activities according to the nationality of the actors.

我们将看到越来越多激进的政府政策，这些政策根据企业的国籍来区分经济活动。

If we can prove the independence of an axiomatic system, then we can guarantee the conciseness of this system, ie.

如果能够证明某个一阶谓词系统的独立性，那么就能够保证该系统的建立是精炼的，即没有任何一条公理或推理规则是多余的。