查询词典 alkynes

A conjugate addition of alkadienyl carbonyl compound with vinyl palladium intermediates which can be formed from oxypalladation of alkynes or allenes was studied, and 1, 6-addition products were obtained.

发现不饱和烃的分子内氧钯化得到的烯基钯中间体能够与不饱和共轭双烯的醛酮反应，选择性的得到1，6-加成产物。

To optimize the reaction condition for the purpose of target compounds synthesis, the advance of 1,3-dipolar cycloaddition and click chemistry is reviewed. The conditions of the reaction between azides or nitrile oxides and terminal alkynes were optimized experimentally and the best operation condition was established.

论文综述了偶极环加成反应和点击化学的进展，特别对Cu催化的腈氧化物或叠氮化物与端炔化合物之间的1，3-偶极环加成反应进行了理论分析与实验研究对反应条件进行了优化，确立了实验室中进行反应的最佳操作条件。

To optimize the reaction condition for the purpose of target compounds synthesis, the advance of 1,3-dipolar cycloaddition and click chemistry is reviewed. The conditions of the reaction between azides or nitrile oxides and terminal alkynes were optimized experimentally and the best operation condition was established.

以此为核心，以价廉易得的小分子原料通过数步反应，分别合成了异噁唑、三氮唑杂环取代(来源：29ABceC论文网www.abclunwen.com)的甲烷衍生物和三嗪联三氮唑杂环衍生物这两个比较有意义的小分子化合物库，达到了分子的多样化。

The copper-catalyzed 1,3-dipolar cycloaddition of alkynes with azides is a typical example of "click" reaction.1 Since the reaction enjoys the advantages of high efficiency and regioselectivity and requires mild reaction conditions and simple purification procedures, it has become a versatile synthetic tool with applicability in diverse areas including bioconjugation and surface modification.2 The click reaction has also been utilized in polymer science with emphasis on the functionalization of preformed polymers through postpolymerization approaches.3 The effort of developing the reaction into a new polymerization technique, however, has met with only limited success.

登录后回答可以获得经验值奖励，并可以查看和管理所有的回答。登录|铜催化1，3偶极环加成反应的炔烃与叠氮化物是&点击&自reaction.1典型的例子反应享有高效率的优势和区域选择性并要求反应条件温和，简单净化程序，它已成为一个多功能综合工具在包括生物耦合和不同领域的适用性表面modification.2的点击反应亦是利用聚合物科学与功能化的重点通过postpolymerization approaches.3预制聚合物发展到一个新的聚合反应的努力技术，然而，只取得有限的成功。

The correlation coefficients between 0X, 1X, 0X(superscript ' subscript D), 1X(superscript ' subscript D) and boiling points for 80 alkenes, 39 alkynes and 169 aliphatic unsaturated hydrocarbons were made, which were 0, 999 3, 0, 999 6, 0. 995 5, respectively and better than those of the famous Kiers index (superscript mX.

其逆指数0阶、1阶指数0X(下标 D，1X，0X，1X分别与80个单烯烃、39个单炔烃、169个不饱和烃的沸点进行相关，复相关系数依次为0.9993，0.9996，0.9955，均优于著名Kier指数(上标 mX的回归结果。

Since historical times,England ,where the early inhabitants were Celts, has been conquered three times .

从有历史以来，英国，在此地早期居住的是凯尔特人，已经被征服了三次。

Bluetooth OBEX File Transfer Enables the sending and receiving of files on your phone via Bluetooth.

蓝牙OBEX文件移动允许经过蓝牙传送和接受文件。。。。