查询词典 alkyne

The preparation method comprises monomer synthesis and polymer synthesis. The polymer synthesis is that cyclopentadienyl sodium monomer is added into metallic cobalt complex-triphenyl phosphorus cobalt chloride under strict oxygen-free and water-free conditions, and then double inner alkyne or outer alkyne conjugate monomer is added in, and after reaction, the precipitation, filtering, abstersion and vacuum-drying are carried out, the large molecules polymer containing cyclopentadienyl cobaltocenium organometallic cobalt is obtained.

制备方法，包括单体合成和聚合物的合成，聚合物的合成是在严格无氧无水条件下，在金属钴配合物三-三苯基磷氯化钴，加入环戊二烯钠单体，随后加入双内炔或双外炔共轭单体，反应后沉淀，过滤，洗涤，真空干燥，得到含环戊二烯茂钴有机金属钴的大分子聚合物。

The average relativeerror was 3.63%, less much than mostly used group-contribution methods for alkyne, chlorine derivative, iodine derivative, especially for alkane, bromine derivative, aromatic hydrocarbon, alicyclic hydrocarbon and sulfur-containing organic compounds.

对4068种有机物的正常沸点进行了估算，其平均相对误差为3.63%，总体估算精度明显优于相比较的基团贡献法，对炔烃、氯衍生物、碘衍生物，尤其是对烷烃类、溴衍生物、芳烃、脂环烃和含硫化合物的估算误差明显减小。

This method can be used to calculate the molar refraction of alkyne from molecular structure.

基团贡献法是根据分子中的基团计算分子性能的方法，具有适用范围广的特点，但对同分异构体的区分能力较差，对分子性能的计算结果误差较大。

Bond breaking and the formation of alkyne end groups and free radicals were observed.

采用多种手段研究了35MeV/u的Ar离子辐照聚酯膜产生的微观结构变化。

The mechanisms of the ruthenium-catalyzed reaction of organic azide with terminal alkyne have been investigated using density functional theory.

采用密度泛函理论，对在Ru催化剂存在下，有机叠氮化合物和末端炔的反应机理作了深入理论研究。

The alkyne group and bromide atom were introduced onto PS end by a series of modification of the functional group.

通过水解位于HPG和PS链之间的酯键测定PS-b-PEO和HPG-g-的分子量和组成。

Based on characteristics and connectivity of the groups in molecules,the group contribution method and topological method was combined together,a new method was developed which can be used to calculate the density of alkyne from molecular structure.

根据分子中基团的特性和连接性，将基团贡献法和拓扑方法结合在一起，发展了一种计算炔烃密度的新方法———基团键贡献法，该方法具有基团贡献法适用范围广和拓扑方法计算结果准确可靠的特点。

In this novel cyclization, nucleophiles very regioselectively attack the internal C1′alkyne carbon of enediynes to give benzene derivatives as a single regioisomer.

在这新的环化，亲核攻击非常regioselectively内部C1'alkyne碳的enediynes给予苯衍生物作为一个单一的regioisomer 。

In order to void sulphur corrosion of steel surface layer when it is heated,in addition to more requirement of material surface quality,this paper gives some measure that alkyne gas of producer is given a desulfidation process by controlling the atmosphere in the producer and that use the alkyne of low sulphur and without smoke as row material.

为避免加热时对钢表层的硫腐蚀，除对材料表面质量提出了进一步的要求外，还提出了采用可控气氛，对发生炉煤气进行脱硫处理及使用低硫无烟煤作发生炉煤气的原料等解决措施。

A novel zwitterion derived from the addition of thiazole carbene to ketene was discovered and captured by an activated alkyne. In this process, we developed a facile and efficient three-component tandem reaction involving thiazole or benzothiazole carbene, disubstituted ketene and activated alkyne.

我们发现了一种新的噻唑卡宾和烯酮形成的两性离子的存在，并用活泼炔成功捕捉，从而发展了一个新的噻唑卡宾或苯并噻唑卡宾、二取代烯酮和活泼炔的三组分串联反应。

Graf, without question, is the greatest women's player in history.

格拉芙，现在，毫无疑问是女子网坛历史上最伟大的选手。

If not, you will have to look around at all your important data.

如果没有，您将需要检查所有的重要数据。