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alder相关的网络例句

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In addition, ioding was found to be an efficient catalyst for the imino Diels-Alder reaction of N-arylimine and enol ethers and the reaction provided tertrahydroqinolines in good yields. One pot synthesis of tetrahydroqinolines from aldehyde, aniline and enol ethers was also achieved using iodine as the catalyst. The chemical yield of the"one pot"reaction was comparable with that obtained using preformed N-arylimine.

此外我们也发现碘能够有效地催化N-芳基亚胺与烯醇醚的Diels-Alder反应,以很高的化学收率得到了四氢喹啉衍生物,并且发现碘也能够直接催化芳香醛、苯胺、烯醇醚的三组分&一锅&反应,获得的化学产率与使用预制的N-芳基亚胺相当。

Diels-Alder reaction between β-myrcene and maleic anhydride catalyzed by SO(superscript 2- subscript 4)/TiO2-ZrO2 solid superacid was investigated.

研究了SO(上标 2-下标 4)/TiO2-ZrO2型固体超强酸催化剂的制备及其催化β-月桂烯与马来酸酐的Diels-Alder反应,通过GC、GC-MS和红外分析,确定其主产物为4-(4-甲基-3-戊烯基)-4-环己烯-1,2-酸酐。

Linear dimerization of isoprene to form myrcene ;2. Synthesis of Unsaturated Cyclothioethers byCycloaddition Reactions of Myrcene;3. The traditional synthesis is by the way of Diels-Alder reaction of myrcene with acrolein over Lewis acid catalysts in organic solvent.

二烷基咪唑或烷基吡啶卤化物与ZnCl2 构成一类新型的具有Lewis酸性的离子液体,以其为催化剂和反应介质,通过月桂烯与丙烯醛的Diels Alder反应高区域选择性地合成了对位柑菁醛。

Synthesis and Structural Analysis of New Monoterpene Derivatives from β-myrcene ;2. Diels-Alder reaction between β-myrcene and maleic anhydride catalyzed by SO2-4/TiO2-ZrO2 solid superacid was investigated.

研究了SO42-/TiO2-ZrO2型固体超强酸催化剂的制备及其催化β-月桂烯与马来酸酐的Diels-Alder反应,通过GC、GC-MS和红外分析,确定其主产物为4-(4-甲基-3-戊烯基)-4-环己烯-1,2-酸酐。

Instead, as in all areas of medicine, physicians need to tailor therapy to patients' specific needs. For ADHD patients who have a history of substance abuse, for example, the treating psychiatrist may want to start treatment with a nonstimulant therapy. If the treatment is not adequate, the second choice would be a long-acting stimulant coupled with rigorous monitoring."Because the stimulants used to treat ADHD are controlled substances, there is built-in monitoring," Dr. Alder said."However, we can watch such patients with extra care for warning signs such as early refills."

另外,Alder医师表示,所有的治疗都一样,医师们必须要对患者的特定需求,量身订制一套治疗法;对於有药物滥用纪录的ADHD患者,举例而言,医师们可以先使用非兴奋剂作治疗,若不合适,第二个选择就是长效型的兴奋剂,再辅以密集的监控;因为用以治疗ADHD的性奋剂都属於管制药物,所以都会有著必要的监控要求;无论如何,我们还是可以从患者的一些徵兆看出,如提早作药物补充等迹象。

Instead, as in all areas of medicine, physicians need to tailor therapy to patients' specific needs. For ADHD patients who have a history of substance abuse, for example, the treating psychiatrist may want to start treatment with a nonstimulant therapy. If the treatment is not adequate, the second choice would be a long-acting stimulant coupled with rigorous monitoring."Because the stimulants used to treat ADHD are controlled substances, there is built-in monitoring," Dr. Alder said."However, we can watch such patients with extra care for warning signs such as early refills."

另外,Alder医师表示,所有的治疗都一样,医师们必须要对患者的特定需求,量身订制一套治疗法;对于有药物滥用纪录的ADHD患者,举例而言,医师们可以先使用非兴奋剂作治疗,若不合适,第二个选择就是长效型的兴奋剂,再辅以密集的监控;因为用以治疗ADHD的性奋剂都属于管制药物,所以都会有著必要的监控要求;无论如何,我们还是可以从患者的一些征兆看出,如提早作药物补充等迹象。

In this dissertation, electrophilic reactions of Nitrosonium with imines, aza-Diels-Alder reactions of N-arylimines with a variety of electron rich olefinic compounds induced by NO~+, and photoreactions of N-nitrosodiphenylamine with aromatic amines were studied.

本文研究了:(1)NO~+与亚胺双健发生的亲电反应;(2)NO~+引发的芳香亚胺和富电子碳碳双键作为亲二烯体的氮杂Diels-Alder反应,高选择性地得到了一系列四氢喹啉的衍生物;(3)N—亚硝基二苯胺与芳香胺发生光化学反应得到了一系列偶氮苯类化合物。

The thesis consists of two main sections. The synthesis of 1,3,4-thiadiazoles,triazolotriazines and dioxapyrrolinopyrazoles containing chiral pyrazolyl moietyfrom D-glucose is described in the first part and the section one is about theDiels-Alder reactions between dienophile enaminones and diene 1,2,4-triazines,which provides a new methodology to construct the pyridine compounds. A total of37 new compounds were synthesized.

本论文包含两部分内容,一是以D-葡萄糖为原料合成含手性吡唑基的1,3,4-噁二唑、三唑并三嗪及二氧代吡咯啉并吡唑类化合物;二是将烯胺酮作为亲双烯体,与双烯体1,2,4-三嗪类化合物发生Diels-Alder反应,发现了一令人意外的构建吡啶类化合物的新方法。

Quinonyl compounds were reducted to phenolic compounds in high yields promoted by aluminum triiodide ,and after the reaction with dienophiles in Diels Alder reactions concave adductions were combined.

在现场制备的三碘化铝促进下,醌类化合物发生还原反应以良好产率生成酚类物,并且在原位与亲双烯体发生Diels Alder反应从而生成凹状加合

The cis-decalin 79 was obtained from 2-methoxy-4-methylphenol (77) via a sequence of reactions involving intermolecular Diels-Alder reaction of masked o-benzoquinone derived from 77 and ethyl vinyl ketone, silyl enol ether formation and Cope rearrangement.

第一部份:以2-甲氧基-4-甲基酚(77)为起始物,经由二乙醯基亚碘苯氧化、分子间Diels-Alder反应、烯醇矽醚的形成及Cope重排反应得到具有十氢萘骨架化合物79。

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