查询词典 aldehyde condensation

Acetaldehyde generated from the 2 - butene aldehyde carbonyl and the reaction is the condensation of methylene ...

由乙醛生成2－丁烯醛的反应是羰基与亚甲基发生缩合的。。。

It was found that condensation reactions of indoles with aldehyde proceeded smoothly in high yields at room temperature.

相比较而言，在同样反应条件下，双吲哚烷基化合物的合成比三吲哚烷基化合物的合成更容易。

The brown color of lecithin is largely the result of heathing the oil during solvent stripping and is to be the result of an aldehyde-amine reaction or aldol condensation.

大豆磷脂中的褐色物质可能是毛油在汽提时生成的，据认为是缩醛产物。

In this section, we focused on the investigation of the condensation, Michael reaction of different aromatic aldehyde with different aryl substituted ketones under solvent-free and PTC conditions, obtained polysubstitutedcyclohexanol derivatives in mordent yield when using TBAB as the catalyst.

通过实验发现，TBAB对该反应具有良好的促进作用，使在液相中需十几个小时甚至几十个小时才能完成的反应，在无溶剂条件下几分钟就可完成，并且使液相中两步完成的反应，而在无溶剂条件下一步就可完成，且产率优良。

Crotonaldehyde aldehyde is acetaldehyde as raw materials, as a condensation NaOH solution extraction, manufacturing sorbic acid is the main raw material.

巴豆醛是以乙醛为原料，经NaOH溶液萃取缩合产生，是制造山梨酸的主要原料。

The crotonaldehyde is produced upon catalysis and condensation with acetic aldehyde as raw materials. It is a major raw material for making sorbic acid.

巴豆醛是以乙醛为原料，经NaOH催化缩合产生，是制造山梨酸的主要原料。

Knoevenagel condensation reaction between aromatic aldehyde, malononitrile or ethyl cyanoacetate is promoted by organocatalyst N-methylimidazole.

以1-甲基咪唑为有机小分子催化剂催化芳香醛与丙二腈或氰乙酸乙酯的Knoevenagel缩合反应，反应速度快，操作方便，产率高，后处理简单。

Subsequently,enol methylation of P in basic condition completed the synthesis of malyngamide O.Applied this route to the synthesis of malyngamides Q and R,the chiral unsaturated acid was connected with the vinyl chloride part by amidation,then the resulting product was converted into the corresponding aldehyde,followed by aldol condensation of the aldehyde with the chlorotitanium enolate of pyrrolidone to complete the skeleton of malyngamides Q and R,then the synthesis of them was completed via enol methylation in acid condition.

该合成路线拓展应用到malyngamides Q和R的合成时，首先用酰胺键将手性不饱和脂肪酸和烯氯片段连接，再转化成相应的醛，与乙酰基吡咯酮进行TiCl_4催化的aldol反应即得到malyngamides Q和R的骨架结构，再经过酸催化的烯醇甲基化反应完成了Q和R的全合成。

The first synthetic route uses 1,2,4-trimethoxybenzene and chloroacetonitrile in forming 2,4,5-trimethoxy-a-chlor-acetophenone under the anhydrous condition, then the intermediate condensates with papaverine forming the core pyrro[2,l-a]isoquinoline, followed by formation and lactonization to form the lactone ring. The second synthetic route uses prepared aldehyde with prepared ethyl nitroacetate by Knoevenagel condensation to obtain 2-Nitro-3-(2,4,5-tris-methoxy-phenyl)-acrylic acid ethyl ester and 2-Nitro-3-(2,4,5-tris-benzyloxy -phenyl)-acrylic acid ethyl ester etal intermediates. The lamellarin skeleton could arise from condensation of the papaverine and these intermediates by Michael reaction, the ester group is provided for subsequent lactonization. The third synthetic route uses coumarin or indan-l,3-dione derivatives and papaverine to form lamellarin under basic conditions.

第一条路线首先从1，2，4-三甲氧基苯出发与卤乙腈作用合成卤代芳酮中间体，然后与罂粟碱反应合成开链片螺素，最后经乙酰化、去保护、成内酯环得到片螺素；第二条路线由制备的芳醛和制备的硝基乙酸乙酯经缩合得到2-硝基-3-芳基丙烯酸乙酯，然后由该中间体与罂粟碱反应，在完成关环的同时也引入酯基，最后去保护、成内酯环得到片螺素；第三条路线是由香豆素或茚二酮出发，经溴代后的中间体与罂粟碱反应，得到片螺素的基本框架。

Papers in the experimental part of our literature considered on the basis of the experimental exploration, and podophyllotoxin intermediates with the structural characteristics of a simple pepper aldehyde as the starting material,α,β-unsaturated carbonyl compounds are selective reduction lithium aluminum hydrogen reduction reaction as the key steps to have the Knoevenagel condensation, peracetic acid epoxy between chlorine and alkaline hydrogen peroxide epoxy, DCC condensation esterification reaction of the three podophyllotoxin intermediates.

论文实验部分我们在综合考虑文献的基础上，经过实验摸索，并结合鬼臼毒素中间体的结构特点以简单的胡椒醛为起始原料，对α，β-不饱和羰基化合物具有选择性还原的锂铝氢还原反应为关键步骤，先后经过Knoevenagel缩合，间氯过氧苯甲酸环氧化，碱性过氧化氢环氧化，DCC缩合酯化等反应合成了3个鬼臼毒素中间体。

Objective: To study the effect of polycythemia on blood oxygen saturation.

裴蕾目的：观察RBC剧增而引起的高粘血症对血氧饱和度的影响。

Based on SIMPLER algorithm in the curvilinear body-fitted coordinates, the calculations were performed for Pr=0.7, Re=10~1000 on non-orthogonal non-staggered grids which are generated by elliptic equation systems.

采用曲线坐标系下压力与速度耦合的SIMPLER算法，数值研究了周期性渐扩渐缩波纹通道内脉动流动与换热情况，流动Re数的范围为10~1000，Pr数为0.7。