查询词典 addition reaction

The influence of different substituents to the addition reaction also has been investigated to research into the reaction law.

优化得到各驻点的几何构型，通过振动分析和内禀反应坐标对过渡态进行了确认，解析了反应路径。

Addition reaction is an organic reaction , it occurs in a double bond or triple bond of the substance.

加成反应是一种有机化学反应，它发生在有双键或叁键的物质中。

By means of GC, GC-MS, GC-IR, the reaction products were investigated and the results showed that there are triylene, camphene, limonene, p-cymene, terpinolene -terpinene,-terpinene,-fenchyl formate, linalyl formate, terpinyl formate, bornyl formate and isobornyl formate containing in the products,and linalyl formate was first discovered in addition reaction of a -pinene and formic acid .The content of the main product terpinyl formate is up to 60.4%,the selectivity is 64.5%.

采用GC、GC-IR、GC-MS等对反应产物进行定量和定性分析，结果表明：微波辐射下α-蒎烯与甲酸的反应产物含有三环烯、莰烯、对-伞花烃、α-松油烯、γ-松油烯、柠檬烯、异松油烯、甲酸葑醇酯、甲酸异龙脑酯、甲酸龙脑酯、甲酸芳樟酯、甲酸松油酯。

We investigate the reaction involving alkynes and α-halophenylethanone in presence of catalyzer to occur nucleophilic addition reaction.

我们还对炔烃与α-卤代苯乙酮在催化剂存在下发生亲核加成反应做了一系列的探索。

The addition reaction of diazo pyrazoles and isocyanate has been investigated and the mechanism of this reaction has been guessed.

研究了重氮基吡唑同异氰酸酯的环加成反应，初步推测了该反应的机理。利用此反应设计了一类可能具有生物活性的吡唑骈[5，1-d][1，2，3，5]四嗪-4-酮类衍生物。

Analyse and compare what adopt a variety of pair of methods, the Michael addition reaction of ester of acerbity second of second of hydroxyl of protection of benzyl of the response of close nucleus addition that uses second nitrile and ester of formic acid second certainly, chloridize, cyanogen, reaction that take off carboxyl generates 3- benzyl oxygen radical the fifth of the ten Heavenly Stem the method of 2 nitrile, detailed discussion the action that wait and the by-product that arise possibly reach the reactant in each pace reaction, activator, dissolvent avoid a method.

通过对多种方法的分析和比较，确定采用乙腈和甲酸乙酯的亲核加成反应、氯化苄保护羟基、氰乙酸乙酯的Michael加成反应、脱羧反应生成3-苄氧基戊二腈的方法，并具体的讨论了每一步反应中反应物、催化剂、溶剂等的功能和可能产生的副产物及避免方法。

The dissertation mainly consists of two parts:1. The Reaction Chemistry of Alkynes under Palladium Catalysis Part 1 studies the reaction α,β-unsaturated carbonyl compounds with alkenylpalladium intermediate generated by nucleopalladation, and discovered 1 the Pd-catalyzed tandem addition reaction of halides, alkynes and α,β-unsaturated carbonyls,2 the four-component tandem addition reaction of halides, alkynes and α,β-unsaturated carbonyls, 3 the tandem intramolecular oxypalladation-conjugate additionreaction of alkynoic acids with α,β-enals. These new reactions provide notonly efficient highly stereoselective methods for the synthesis of γ,δ-unsaturated,polyunsaturated carbonyl compounds and γ-lactonic aldehydes, but also thebasic transformations for a number of C-C bond formation reactions which can be usedto design synthesis of many acyclic, cyclic or polycyclic compounds.

本论文的主要工作分为两个部分：一、钯催化下炔烃的反应化学在本小组前人工作的基础上，我们详细研究了炔烃亲核钯化产生的烯基钯中间体与α，β-不饱和羰基化合物的反应，发现两价钯催化下卤离子-炔烃-α，β-不饱和醛酮的串联加成反应、卤离子-炔烃-α，β-不饱和醛酮的西组分串联加成及炔酸分子内氧钯化-串联Michael型加成反应；由此发展了γ，δ-不饱和醛酮、多不饱和羰基化合物和带有醛酮基侧链的γ-丁内酯衍生物的高立体选择性合成方法，这一过量卤离子存在下的烯基钯对α，β-不饱和羰基化合物共轭加成反应的发现，为大量碳-碳键形成反应的实现提供了基础，使我们能够从这一基本反应出发，设计和开发多种分子内、分子间的碳碳成键反应，以好的立体、区域选择性组建开链、环状及多环类型的化合物。

For example,the addition reaction with small molecular,the metathetical reaction with alkynes and Wittig reaction to prepare high-valent transtion-metal allenylidene complexes.

对于化合物11，详细研究了其与小分子加成反应、炔烃复分解反应以及通过Wittig反应制备高价态过渡金属丙二烯基卡宾化合物。

Effects of microwave power, reaction time, reaction temperature, solvent etc. on reaction were studied by a single factor tests. The results show that maleic acid is more active than fumaric acid; the introduction of methyl group on the double bond can weak the reactivity of the Michael addition reaction; the ester base is more propitious to complete the Michael addition reaction than the nitrile base.

为研究微波下迈克尔反应的规律，本文采用单模聚焦微波有机合成仪，通过对顺丁烯二酸、反丁烯二酸和氨水合成DL-天冬氨酸、顺式3-甲基丁烯二酸和氨水合成3-甲基天冬氨酸、丙烯酸甲酯和氨水合成β-丙氨酸、丙烯腈和氨水合成β-氨基丙腈等五个反应对迈克尔加成反应进行了研究。

Halogen, proton acids, sub-halogen acid are electrophilic reagents, olefin addition reaction is the electrophilic addition reaction .

卤素、质子酸，次卤酸等都是亲电试剂，烯烃的加成反应是亲电加成反应。

Graf, without question, is the greatest women's player in history.

格拉芙，现在，毫无疑问是女子网坛历史上最伟大的选手。

If not, you will have to look around at all your important data.

如果没有，您将需要检查所有的重要数据。