炔

与炔相关的网络例句 [注：此内容来源于网络，仅供参考]

Results showed that the alkynol compounds were transformed to the corresponding alkyne aldehyde and acetylenic acid compounds containing conjugated system on the nickel anode, and hence the anodic oxidation reaction products were able to generate ultraviolet absorption.

结果表明，炔醇类化合物在阳极生成了相应的有共扼体系的炔醛类和炔酸类化合物，产生了紫外吸收。

Calcium carbide production, dissolved acetylene, self-diol, has been acetylenic diol, a hybroxybutyric alcohol, methyl amyl alcohol, without the others methyl diol and other products.

主要生产碳化钙、溶解乙炔、己二醇、己炔二醇、甲基丁炔醇、甲基戊炔醇、不带甲基的己二醇等产品。

In the first part, one of the side-arms of hexakisbenzene was replaced with a 4-pyridinylethynyl group. Comparing with analogous compounds incorporating a 2- or 3-pyridinylethynyl moiety, the compound with a 4-pyridinyl -ethynyl unit shows lowest melting and clearing points.

中文摘要系列一部分为在六炔苯基苯盘形分子上引入一对位吡啶炔侧臂，在与引入邻位、间位的分子相比较后，发现含对位吡啶炔侧臂的化合物其澄清点温度最低且无热分解问题。

The chapter two was focused on the samarium diiodide promoted organic reactions and their applications in organic synthesis, firstly, a new synthesis of highly substituted cyclopentadienes from a,β-alkynone promoted by samarium diiodide was investigated and the highly substituted cyclopentadienes were prepared in moderate to good yields under mild conditions. Secondly, the Michael addition and Michael-aldol tandem reaction of diorganyl diselenides or diorganyl disulfides with α,β-alkynones mediated by samarium diiodide were studied and a series of alkenylsulfides and alkenylselenides were prepared in good yields. Then the highly regioselecfive nucleophilic addition of the allylsamarium bromide to α,β-alkynones were explored. We found that the allylsamarium bromide reacts with α,β-alkynones to afford regiospecificly 1. 2-nucleophilic addition products in good yields under mild condition. At last we studied the coupling reaction of aryl halides promoted by NiCl〓/PPh〓/Sm〓.

第二章 研究了二碘化钐、金属钐促进的有机反应：1、二碘化钐促进下α，β-炔基酮的偶联环化反应，提供了一种制备多取代环戊二烯的新方法；2、二碘化钐促进下的二硫醚、二硒醚与α，β-炔基酮的Michael加成反应，为高产率地制备多取代的烯基硫或烯基硒化合物提供了方便可靠的新方法；3、二碘化钐促进下的二硫醚、二硒醚与α，β-炔基酮和醛、酮的Michael—aldol串联反应，提供了一种一锅法高产率地制备多取代的含硫的烯丙基醇或含硒的烯丙基醇类化合物的方便可靠的原子经济性的新方法；4、烯丙基溴化钐与α，β-炔基酮的高度区域选择性的1，2-亲核加成反应；5、NiCl〓/PPh〓/Sm〓促进的卤代芳烃的偶联反应-一种从各种卤代芳烃制备联苯类化合物的有效方法。

Firstly, the reactions of glutaric acid, sebacic acid and propargyl alcohol afforded two dipropargylesters:(CH≡CCH_2OCO)_2(CH_2)_3 (compound 1) and (CH≡CCH_2OCO)_2 (CH_2)_8 (compound 2),respectively.

首先，本文分别选用戊二酸，癸二酸与丙炔醇反应得到了两个新的有机二酸二丙炔醇酯：戊二酸二丙炔醇酯(CH≡CCH_2OCO)_2(CH_2)_3(化合物1)和癸二酸二丙炔醇酯(CH≡CCH_2OCO)_2(CH_2)_8(化合物2)。

The results showed polymeric diaryliodonium salts were effective aryl ion transfer reagents. Thirdly, a new type polymer supported hypervalent iodine reagents poly { [4-Hydroxy iodo] styrene} has been developed. It was an effective oxidative reagent, and could be applied to the one pot synthesis of 4-arylthiazoles.

然后，我们以聚苯乙烯羟基对甲苯磺酰氧基碘苯为原料，成功制备了一类新型聚合物高碘试剂—聚苯乙烯负载的炔基碘盐，并研究了其作为炔基转移试剂的有效性：(1)该试剂可对硫、氮、硒等负离子进行亲电炔基化反应，合成炔基亚砜、0，0-二烃基二硫代磷酸炔基酯、1-苯乙炔基苯并噻唑以及炔基硒醚。

The dissertation mainly consists of two parts:1. The Reaction Chemistry of Alkynes under Palladium Catalysis Part 1 studies the reaction α,β-unsaturated carbonyl compounds with alkenylpalladium intermediate generated by nucleopalladation, and discovered 1 the Pd-catalyzed tandem addition reaction of halides, alkynes and α,β-unsaturated carbonyls,2 the four-component tandem addition reaction of halides, alkynes and α,β-unsaturated carbonyls, 3 the tandem intramolecular oxypalladation-conjugate additionreaction of alkynoic acids with α,β-enals. These new reactions provide notonly efficient highly stereoselective methods for the synthesis of γ,δ-unsaturated,polyunsaturated carbonyl compounds and γ-lactonic aldehydes, but also thebasic transformations for a number of C-C bond formation reactions which can be usedto design synthesis of many acyclic, cyclic or polycyclic compounds.

本论文的主要工作分为两个部分：一、钯催化下炔烃的反应化学在本小组前人工作的基础上，我们详细研究了炔烃亲核钯化产生的烯基钯中间体与α，β-不饱和羰基化合物的反应，发现两价钯催化下卤离子-炔烃-α，β-不饱和醛酮的串联加成反应、卤离子-炔烃-α，β-不饱和醛酮的西组分串联加成及炔酸分子内氧钯化-串联Michael型加成反应；由此发展了γ，δ-不饱和醛酮、多不饱和羰基化合物和带有醛酮基侧链的γ-丁内酯衍生物的高立体选择性合成方法，这一过量卤离子存在下的烯基钯对α，β-不饱和羰基化合物共轭加成反应的发现，为大量碳-碳键形成反应的实现提供了基础，使我们能够从这一基本反应出发，设计和开发多种分子内、分子间的碳碳成键反应，以好的立体、区域选择性组建开链、环状及多环类型的化合物。

Have been investigated for the first time, obtaining poly , copolymers of para-diethynylbenzere with propargyl alcohol , propiolic acid with ethynylbenzene , propiolic acid with para-diethynylbenzene, and propiolic acid with propargyl alcohol.

制得丙炔酸均聚物，以及对二乙炔苯与丙炔醇，丙炔酸与苯乙炔，丙炔酸与对二乙炔苯，丙炔酸与丙炔醇共聚物。

In addition, the new phosphine-catalyzed cyclization reactions of dimethylacetylenedicarboxylate and methyl propiolate with N-tosylimines are also described.

发展了膦催化下丁炔二酸二甲酯和丙炔酸甲酯与贫电子亚胺的环化反应，这对2-炔酸酯的反应又是一个补充，进一步丰富了膦催化下贫电子炔烃的反应化学。

The normally brominated Baylis-Hillman adducts were formed as the major product at low temperature. While at room temperature or heating, the α,γand β,β-dibrominated compounds were formed as the major products using 3-butyn-2-one and methyl propiolate or propynenitrile as substrate, respectively.

贫电子炔类化合物的Baylis-Hillman反应的研究在这部分工作中我们发现在用TiBr〓或BBr〓为Lewis酸催化贫电子炔类化合物和芳香醛的Baylis-Hillman反应时，温度对反应的影响很大：当反应在低温下进行时，通常生成的是正常的β-溴代的Baylis-Hillman反应产物；而在室温或加热条件下反应，以丁炔酮为底物时，主要生成的是α，γ-二溴化合物，而以丙炔酸甲酯及丙炔腈为底物时，主要生成的是β，β-二溴化合物。

与炔相关的网络解释 [注：此内容来源于网络，仅供参考]

alkyne：炔; 链炔烃

alkylphosphonothio dihalide 烷基硫代膦酰二卤 | alkyne 炔; 链炔烃 | alleviating measures 缓和措施; 减轻措施

alkyne series：炔系 炔属烃

alkylsulfonate | 烷基磺酸盐(或酯) | alkyne series | 炔系 炔属烃 | alkyne | 炔

acetylenes; alkyne：炔类{炔属烃}

"acetylene welding set","乙炔熔接装置" | "acetylenes; alkyne","炔类{炔属烃}" | "acetylenic acid","炔[属]酸"

oxyacetylene torch：氧炔焊炬

oxyacetylene cutting 氧炔切割 | oxyacetylene torch 氧炔焊炬 | oxyacetylene welding 氧炔焊

oxyacetylene cutting：氧炔切割

oxyacetylene burner 氧炔焊炬 | oxyacetylene cutting 氧炔切割 | oxyacetylene torch 氧炔焊炬

propargyl acetate：乙酸炔丙酯;醋酸炔丙酯

丙[酸]酐 propanoic acid anhydride | 乙酸炔丙酯;醋酸炔丙酯 propargyl acetate | 炔丙醛;丙炔醛 propargyl aldehyde

propargyl aldehyde：炔丙醛;丙炔醛

乙酸炔丙酯;醋酸炔丙酯 propargyl acetate | 炔丙醛;丙炔醛 propargyl aldehyde | 炔丙酸;丙炔酸 propargylic acid

propargylic acid：炔丙酸,丙炔酸

炔丙醛;丙炔醛 propargyl aldehyde | 炔丙酸;丙炔酸 propargylic acid | 丙烯醛 propenal; acrolein

propiolic acid; propargylic acid：丙炔酸;炔丙酸

丙炔醛;炔丙醛 propiolaldehyde; propargyl aldehyde | 丙炔酸;炔丙酸 propiolic acid; propargylic acid | 丙醛 propionaldehyde

propiolaldehyde; propargyl aldehyde：丙炔醛;炔丙醛

丙炔 propine; propyne | 丙炔醛;炔丙醛 propiolaldehyde; propargyl aldehyde | 丙炔酸;炔丙酸 propiolic acid; propargylic acid