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The characteristics of pentacene/perylene derivatives based organic solar cells are investigated in this thesis Donor and acceptor layers are pentacene and N N'-dioctyl-3 4 9 10-perylenetetracarboxylic diimide (PTCDI-2~13C) respectively Twelve organic solar cells with pentacene/PTCDI-2~13C heterojunctions were fabricated to study the influence of various alkylic perylene derivatives on the power conversion efficiency Under the sunlight simulator with AM1 5G filter and 100 mW/cm2 the solar cell of pentacene/PTCDI-7C heterojunction with cathode of Ag/Al bilayer has the best performance among the devices with pentacene/PTCDI-2~13C heterojunctions In PL spectrum analyses the pentacene/PTCDI-7C film had lower recombination rate than the other pentacene/PTCDI-2~13C films; therefore more excitons could reach the P/N junction and enhance short-circuit current Furthermore the PTCDI-7C film grown on the surface of penatcene was more matched than other PTCDI films analyzed by the PL peak shifts of 10 nm and 45 nm thick PTCDI-2~13C and images of atomic force microscope More lattice match between the films of pentacene and PTCDI resulted in fewer defects in P/N junction and more carries can reach electrodes Accordingly the power conversion efficiency approach 2% was obtained from the solar cell with the active layer of pentacene/PTCDI-7C

本研究探讨以五环素/骈苯衍生物异质接面太阳能电池之特性,利用pentacene作为电子施体有机材料,PTCDI -2C~13C作为电子受体有机材料,制作出异质接面为pentacene/ PTCDI-2C ~13C等12种有机太阳能电池,比较不同碳数的骈苯衍生物对於有机太阳能电池之光电转换效率之影响。在AM1 5G、100 mW/cm2的模拟太阳光下,以pentacene/PTCDI-7C异质接面太阳能电池具有短路电流9 882 mA/cm2、开路电压0 376 V、填充因数0 523及光电转换效率达1 945%,皆比其他pentacene/PTCDI-2C ~13C异质接面太阳能电池来的大。由薄膜分析可知PTCDI-7C在这12种太阳能电池中具有较低的电子电洞复合发光效率,可以让较多激子到达异质接面进行电荷分离,减少电子电洞对复合发光的机率;此外,由光激发萤光光谱之峰值位移配合原子力显微镜表面结构图,可以得知当PTCDI-7C成长在pentacene上时会顺著pentacene的结构成长薄膜,故较无缺陷产生在P/N接面处;而在其他结构下则无此现象产生,致使在pentacene/PTCDI-7C薄膜中的载子有较大的机会可以移动至电极,使光电流提高,进而使光电转换效率提高。

In this paper, a method of analysis which was based on thin layer chromatography was introduced. Benzimidazole derivative and amine were separated at first.

文中采用薄层层析法分离苯并咪唑衍生物及杂质,首先分离出苯并咪唑衍生物,然后用非水滴定方法分析含量,得到了准确的分析结果。

IV. The total synthesis of dehydrodiconiferyl alcohol and its dihydro-derivative The benzofuran skeleton was constructed by chemically oxidative couplingstarting from vanillin, then selective reduction with LiAI〓/〓 andhydrogenation in the presence of Pd-C followed reduction with LiAl〓respectively, to give dehydrodiconideryl alcohol and its dihydro-derivative, usefulin treating and preventing digestive system disorders, esp.

四、Dehydrodiconiferyl alcohol及其二氢衍生物的全合成以香草醛为起始原料,用化学氧化法一步建立氢化苯骈呋喃骨架,LiAlH〓/〓选择性还原以及催化加氢还原接着〓还原,分别合成了对预防和治疗消化系统疾病尤其是胃溃疡有显著效果的Dehydrodiconiferylalcohol及其二氢衍生物

One UV absorber is a benzotriazole derivative, and the other UV absorber is a benzophenone derivative.

一种紫外吸收化合物是苯并三唑衍生物,另一种紫外吸收剂为二苯酮衍生物

In order to improve the catalytic activity, A series of bident ligands containing nitrogen atom were prepared by design, such as bipyridine derivatives, phenantroline derivatives, Schiff base of bipyridine etc.

为了提高催化活性,设计合成一系列含氮双齿配体,如联吡啶衍生物、邻菲罗啉衍生物、含吡啶席夫碱等。

two kinds of ash-less and phosphorous-free compounds, referred to as boma and loma, as lubricating oil additives, were synthesized to replace or partially replace zddp. they were characterized by means of infrared spectroscopy, mass spectroscopy and element analysis.

合成了两种无灰无磷抗磨添加剂:不含三嗪环的含羟基羧酸酯衍生物boma;含羟基的三嗪羧酸酯衍生物loma,分别用元素分析和红外光谱对分子结构进行表征。

Two kinds of water-soluble biomimetic chitosan derivatives with a phosphoramide linkage between glucosamine and choline were prepared through Atherton-Todd reaction under the mild conditions, including zwitterionic phosphorylcholine bound chitosan and acetyl-phosphorylcholine bound chitosan with positive charge. The interaction between chitosan derivatives and calf thymus DNA were inversigated by UV alsorption spectra and circular dichroism spectra.

采用Antherton-Todd反应制备了两种水溶性的磷酰化壳聚糖仿生衍生物:两性的N-磷酸胆碱磷酰化壳聚糖和带正电荷的N-乙基磷酸胆碱磷酰化壳聚糖,并用紫外吸收光谱和圆二色光谱研究了两种胆碱磷酰化壳聚糖衍生物与小牛胸腺DNA的相互作用。

Derivatives of bromine are much more active than the corresponding one of chlorine.

溴的衍生物的活性要比相应的氯的衍生物大得多。

Objective To study the effect of derivative of chitin on fracture healing and further investigate its therapetic mechanism.

目的 探讨甲壳质衍生物在骨折愈合中的作用,并进一步探究甲壳质衍生物对骨折愈合的作用机制。

The reported organocatalyst for asymmetric Michael additions include proline and its derivatives, chiral imidazolidinone derivatives, chiral urea, cinchona alkaloids and so on.

目前报道的催化Michael加成反应的有机催化剂主要有脯氨酸及其衍生物、手性咪唑啉酮、手性脲、金鸡纳碱衍生物等。

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Certain types of sockets are ''connectionless'', most commonly

某些类型的套接字是无连接的,大多数是UDP协议。

Take it in to his nibs yourself .

你自己拿进去给头儿吧。

HoMedics has been around for just over 20 years, and yet in that time they have become recognized as a leader in the health and wellness industry.

HoMedics已经有超过20年,但在那个时候,他们已经成为公认的领导者,在卫生和健康产业。