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While the adsorptions of l-propanol and 1-Br-propane at 100 癈 give rise to 1-propoxy species, which mainly converted to propanal at higher temperature. IR spectrum arising from the interaction of propene with the catalyst at 100 癈 shows the IR bands of allyl alcoholate and isopropoxy species. As the temperature was increased to 150 癈, the bands ascribable to the adsorbed acetone and acrolein were observed. Based on these results, it is suggested that isopropoxy species is one of the intermediates for SOP to acrolein over MoPO/SiO2 catalyst.

原位IR光谱实验结果表明:200℃时丙烷/O_2混合气在催化剂表面吸附后的IR谱与同温度下异丙醇吸附的IR谱相似,均检测到吸附态丙酮物种和丙烯醛物种的IR谱峰;溴代异丙烷和异丙醇在催化剂表面吸附后均转化为异丙氧基,异丙氧基主要转化为丙烯和丙酮,丙烯进一步转化为丙烯醛;溴代正丙烷和正丙醇在催化剂表面吸附后均转化为正丙氧基,正丙氧基主要转化为丙醛;丙烯在催化剂表面吸附后转化为σ-氧烯丙基和异丙氧基,升温后σ-氧烯丙基转化为丙烯醛而异丙氧基转化为丙酮。

When pH is 10, adsorption time is 30 min, dosage of bone char is 0.6 g/L, the original concentration of As in drinking water is 0.5 mg/L, As removal can reach 95.2%. The adsorption behavior is fitted both with Langmuir and Freundlich isotherm. The adsorption mechanism is supposed to be Ca—OH functional groups combined with anion. And there may occur the co-precipitation between calcium hydrogen arsenate and hydroxylapatite in the aqueous solution, and ions also exchange. The saturation adsorption capacity of As reaches 4.688 mg/g. Indexes of effluent are in good agreement with the WHO stringent drinking water standards (0.01 mg/L).

研究结果表明:在pH=10,吸附时间为30 min和骨炭加入量为0.6 g/L,饮用水砷初始质量浓度为0.5 mg/L时其砷去除率可达95.2%;骨炭吸附砷的行为同时符合Langmuir和Freundlich等温吸附模型;其吸附机理可能是Ca—OH官能团结合HASO4阴离子,并产生砷酸氢钙和羟基磷灰石的共沉淀,另外还存在离子交换作用;吸附柱的饱和吸附容量为4.688 mg/g;出水砷浓度符合世界卫生组织规定饮水砷标准(0.01 mg/L)。

The optimized velocity of flow in dynamic adsorption is tenth of the volume of the resin columniation per minute and the adsorbed volume of the solution which contain 101μg/ml activity component of 2507 is 65 time of the volume of the resin columniation. The dynamic adsorption capacity of per gram resin is 9494μg/g, and the adsorption rate is almost 100% because the hydrogen bond may be formed in the adsorption process.

动态吸附最佳的吸附流速为每分钟十分之一个柱体积,在此条件下,可以吸附相当于约65个柱体积的有效组分浓度为101μg/ml的溶液,每克树脂的动态吸附量为9494μg/g,因为可能在吸附过程中有氢键生成,所以吸附率几乎为100%。

In order to remove the phosphorus that causes eutrophication, a new type of dephosphorization absorbent was prepared in the paper. The adsorption of phosphate was studied, and results showed that the adsorption would finished quickly in a short time and in acid solution, the adsorption capacity was 34 mg/g.

针对水体富营养化的磷,采用吸附法进行处理,制备出一种新型的除磷吸附剂,对水中磷酸盐的吸附性能进行了研究,结果表明,该吸附剂对磷酸盐的吸附速率很高,在酸性条件下,其最大吸附容量为34mg/g。

According to thermodynamic function the relation was calculated adsorption of enthalpy of adsorption waiting for a quantity, Gibbs can be mixed freely adsorptive entropy, enthalpy of adsorption waiting for a quantity is in 30 ~ between 40kJ/mol, figure adsorptive process is hydrogenous key adsorption.

根据热力学函数关系计算了等量吸附焓、Gibbs吸附自由能和吸附熵,等量吸附焓在30~40kJ/mol之间,推测吸附过程为氢键吸附

Humic acids, oxidizable fraction and lipids were the main fractions affecting the sorption capacity. The humic acids had the maximum adsorption capacity for nitrobenzene and aniline, the lipids naturally present in the soil strongly compete for hydrophobic sorption sites within the soil organic matter, and the adsorption capacity of mineral surface for nitrobenzene and aniline were only 2.31mg·kg-1 and 3.63mg·kg-1, respectively.

硝基苯和苯胺在湿地土壤中的吸附主要受腐殖酸、易氧化有机质组分和脂类化合物的影响,其中腐殖酸对硝基苯和苯胺具有最大的吸附容量;脂类化合物表现为与硝基苯、苯胺竞争土壤有机质结构中的吸附位点,去除脂类化合物后残余物的吸附量增大;矿物组分对硝基苯和苯胺的吸附是次要的,吸附容量仅为2.31mg·kg-1和3.63mg·kg-1。

The yeast of Saccharomyces cerevisiae is an ideal biomaterial to be used for exploring the mechanism and for actual util...

结合自己的研究成果,总结了酿酒酵母作为生物吸附材料的优点、研究中的表现形式和吸附性能,重点讨论了酿酒酵母生物吸附机理,介绍了等温吸附平衡模型和动力学模型在酵母生物吸附中的应用情况。最后提出生物吸附进一步的研究方向。

The results showed that at the same concentrations, the total amount of test PAHs adsorbed by the K. candel and A. marina leaf litters had no significant difference, in spite of their decomposition status. The adsorbed amount of the PAHs tended to increase with their increasing concentrations. The litters had a higher adsorption rate of or exhibited selective adsorption to phenathrene and chrysene when the PAHs concentrations were lower, and had a higher adsorption rate of benzo perylene when the PAHs concentrations were higher.

结果显示:在同等PAHs浓度下,秋茄和白骨壤落叶碎屑对4种PAHs的吸附总量相近,树种间或分解状态间的吸附差异不显著;随着PAHs浓度的增加,2种红树植物落叶碎屑对4种PAHs的吸附率均呈现逐渐增加的趋势;PAHs浓度较低时,落叶碎屑对和菲有较高的吸附率或选择性吸附,PAHs浓度较高时,落叶碎屑对苯并芘吸附率提高。

It can improve the conflagrant properies of tobacco when cobalt joined, and the min-nim selenium can reduce the deleterious substance in the cigcarette haze, and reduce the harm to health,therefore in this paper we have researched the adsorptive properities of cobalt on tobacco and some factors which affect the adsorption of selenium on tobacco by the theory of liquid - solid adsorption . We have discussed the influences of the adsorbate concentration. temperature, pH and certain concomitant substance, and have determined adsorption isothermal under the different temperature.

微量元素钴的加入能改善烟丝的燃烧性能;微量硒的存在能降低烟气中有害物质,减轻吸烟对人体健康的危害,因此本论文利用固—液吸附理论研究了钴在烟草上的吸附性能以及硒在烟草上吸附的一些影响因素,探讨了吸附质浓度、温度、pH及某些共存物质对吸附的影响,测定了不同温度下的吸附等温线。

Isosteric adsorption enthalpy, adsorption free energy and adsorption entropy were calculated according to the relationship of thermodynamic function.

利用热力学函数关系计算了等量吸附焓、吸附自由能和吸附熵,等量吸附焓在8.95~13.41 kJ/mol之间,推测吸附过程为氢键吸附

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Do not gum up the work by telling mother what we are going to do .

别告诉母亲我们要干的事,那会把事情搞糟的。

In recent years, application of the partial prestressed concrete beam s is developed.

近年来,随着部分预应力砼梁应用的推广,发现我国规范所采用的名义拉应力法的计算结果不稳定。

Gorky once said:"If it is not a book, I'd be stupid and indecent drowning."

高尔基曾说:"如果不是书籍的话,我就要被愚蠢和下流淹死。"