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In this dissertation, two series of rare earth initiators: rare earth tri (2, 6-di-tert-butyl4-methylphenolate) and rare earth calixarene complex have been developed to ring-opening polymerize 2, 2-dimethyltrimethylene carbonate, trimethylene carbonate and ε-caprolactone at mild conditions. Both the polymerization features and mechanisms are discussed in details.

本论文为环碳酸酯、内酯的开环聚合开发了两类新型低毒性稀土催化剂:三(2,6-二叔丁基-4-甲基苯氧基)稀土配合物和对叔丁基杯芳烃稀土配合物,都可以在温和的反应条件下单组分引发2,2-二甲基三亚甲基环碳酸酯、三亚甲基环碳酸酯和ε-己内酯聚合,合成各种分子量的均聚和共聚材料,考察了催化剂结构、聚合条件等对聚合的影响,深入研究了聚合机理。

The reaction of isomerized butadieneiron complex (I; R = Ph, p-tolyl) with triphenylphosphine and tri-Ph phosphite gave products II (same R; R1 = Ph, OPh), at -60 to -30? When I was reacted with triphenylphosphine in hexane at 60 to 70?

丁二烯二羰基铁配合物的异构化产物,C4H62FeC(OC2H5)Ar(1,Ar=苯基, 2, Ar=对甲苯基),在己烷溶液中于-60到-40℃与三苯膦或亚磷酸三苯酯反应生产产物3-6。

In this study, the critical point data of ternary systems which is composed of supercritical carbon dioxide, trisodium salt of tri-(m-sulfonphenyl)phosphine and cosolvent were measured the first time. With the increase of mol% of the cosolvent, critical temperature of ternary system increased, and the experimental data show a linear dependence of critical temperature with mol% of the ternary system over the concentration ranges studied too.

北京化工大学硕士研究生论文本文还首次测试了在超临界CO:中加入三磺化三苯基麟以及共溶剂组成的三元体系的临界点数据,发现三元体系中临界温度也随共溶剂的浓度增加逐渐增加,呈一种线性关系。

TRI P+P algorithm also uses improved parallel star algorithm for the tristate elements to reduce unnecessary fault simulation events.

另外,为了提高故障模拟器的效率,在TRI P+P算法中还引入了改进的并行星算法应用于三态元件。

The final experiments shows that TRI P+P algorithm can not only deal with the sequential circuits containing only 2-valued element but can also deal with the sequential circuit containing both 2-valued elements and tristate elements efficiently.

这样就减少了无效的故障模拟,从而提高了测试的效率,实验结果表明,TRI P+P算法既能处理通常的只含二值元件的时序电路,又能处理含有二值,三值元件的混合时序电路,并且具有较高的效率。

A series of tri-radicals with heterospin center of 1,3,5- trisubstituted benzee as feeomagnetic coupling unit has been studied by using quantum chemical DFT UB3LYP method.

采用量子化学DFT UB3LYP方法,在6-31G基组水平上讨论了以1,3,5-苯为铁磁耦合单元的异自旋中心三自由基体系。

In this dissertation, several novel halogen-free fire-retardant epoxy-based copper clad laminates were developed. Two kinds of phosphrous-containing epoxy resins were synthesized by different method. A novel nitrogen-containing curing agent 2,4, 6-tri (phenol-methylene -amide)-trizone was synthesized for preparing high-performance epoxy polymers, and the synthesis kinetics, cure kinetics and mechanism of MFP cured with DGEBA have been investigated by Differential Scanning Calorimeter and in situ Infrared.

本论文以开发新型无卤阻燃环氧树脂基覆铜板为目标,合成了两类结构不同的含磷环氧树脂以及一种新型的含氮固化剂2,4,6-三-均三嗪,考察了它们合成过程中的影响因素,用DSC和原位红外光谱法探讨了MFP固化环氧树脂的固化反应机理。

Results MRS medium was more suitable for producing bacteriocin than other media. The maximum plantaricin production was obtained in modified MRS medium containing 10 g/L maltose and 10 g/L glucose, 10 g/L yeast extract, 10 g/L tryptone and 2g/L tri-ammonium citrate, 1 mL/L Tween80, 6 g/L K2HPO4 ?

最佳培养基为MRS培养基;优化后的培养基配方为葡萄糖10 g/L,麦芽糖10 g/L,酵母提取物10 g/L,蛋白胨10 g/L,柠檬酸三铵2 g/L,吐温80为1 mL/L,K2HPO4·3H2O 6 g/L,乙酸钠5 g/L,硫酸镁0.2 g/L,硫酸锰

The result indicates that the pulp of the tri ploid of Populus tomen tosa is higher in yield and lower in Kapper's value than that of general Pop ulus tomentosa and its physical properties of unbreached pulp are better too.

研究表明:在相同蒸煮条件下,三倍体毛白杨较普通毛白杨细浆得率高,卡伯值低;浆张强度较普通毛白杨好。三倍体毛白杨的碱性亚纳蒽醌法浆,卡伯值在 18左右时,细浆得率达到 53 %以上,而且浆张强度较好。

Magnetic water was used to cultivate single protein, and then its HNMR was measured along with that of unmagnetized tri-distilled.

在长期静止的情况下,可形成多达几十个水分子的团簇。须指出,这些大分子团是随机的、无定形的链状线团。

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He became prime minister in 1997 and won international acclaim for his role in the Northern Ireland peace process.

他在1997年成为总理,并且因为在北爱尔兰的和平进程中发挥的作用受到国际社会的赞许。

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You can laud them for speaking their minds, or you can criticize them for their big mouth, but you cannot deny that these retorts, rebuttals and asides add much needed color to an otherwise drab portrait of Chinese officialdom.

你可以赞扬他们直抒胸臆,也可以骂他们的大丑嘴巴,但你不能否认,这些反驳和旁白为中国官场众生相添加了新的色彩。