查询词典 supported

Our results reveal that with the same number of cobalt atoms and the same cobalt-substrate interation stength, the melting points and pre-melting intervals of the two kinds of supported Co clusters are all in reasonable agreement with each other. With increasing the depth of supported potential, the melting points increase for the supported cluster. Similar to the case of free clusters, the linear relation between the melting point and the inverse of cluster's size cube root is also found for the two kinds of supported clusters.

结果表明：对于给定原子数目的支撑Co团簇，在衬底势强度相同时，两种衬底势下对支撑团簇熔点及预熔化区间给出了一致的描述；随衬底势强度增加，支撑团簇熔点升高，且两种衬底势所描述的支撑Co团簇也类同于自由Co团簇都表现出较好的熔点与尺寸依赖的线性关系。

Dealcoholization temperature markedly influences the surface area and porosity of the resultant MAO-supports. When the support was pretreated at lower or higher temperature, the corresponding MAO-support shows very low surface area;2.XRD and IR analyses indicate that MAO has reacted with the residual ethanol in the supports, which is an important manner to get MAO fixed on the carrier. Morever, XPS analyse indicates that MAO can also be coordinated with MgCl_2, which is another way to get MAO fixed on the support;3.ICP and EDX analyses indicate that dealcoholization temperature not only determined the element content on the solid catalyst, but also influences the element distribution on the carrier;4.The activities of the supported phenoxy-imine catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature. The support (MSP-5) obtained by treating MgCl_2·2.56C_2H_5OH at 160℃for 4 h, then modified by MAO is very effective for immobilizing complex 3, the resultant solid catalyst (MSPC-5) shows very high activity in ethylene polymerization, and its kinetics of polymerization is stable during the reaction process. Finally, PEs with spherical morphology and high bulk density (over 0.35g/ml) were obtained, without reactor fouling;5.In this work, polymerization conditions such as alkylaluminums, Al/Zr ratio, temperature and H_2 had a pronounced effect on the activity of MSPC-5 and properties of PE;(3). New MgCl_2-Supported Single-Site Catalysts for Ethylene PolymerizationIn this work, a kind of new MgCl_2 support was obtained by anhydrous MgCl_2 co-milled with solid MAO, and it is a creative contribution. Then some single-site catalysts were supported on the new MgCl_2 support, and the resulted solid catalysts were tested in ethylene polymerization, the results indicated that:1.XRD and IR analyses indicate that MAO does be coordinated with MgCl_2, which is in good agreement with the results obtained by XPS;2.co-mlling time had no obvious effect on the texture of support after 12 hours;3.In this work, MgCl_2 was co-milled with solid MAO for different hours, and then complex 3 was supported on these co-milled supports. It was found that co-milling time markedly influences the activity of solid catalysts, but it had negligible effect on the kinetic profile and the properties of resultant PE.

XPS研究结果表明，MAO不仅仅只和乙醇作用，MAO还与MgCl_2本身有一定的作用，这是一个极为重要的发现；3、通过ICP和EDX表征，发现载体的脱醇温度直接影响着元素在固体催化剂中的含量及分布；4、脱醇温度极大地影响着负载苯氧基亚胺类催化剂的活性和聚合物的性能，特别是原始载体经160℃活化4小时制备得到的固体催化剂MSPC-5的活性明显高于其他脱醇温度条件下制得的固体催化，并且催化剂寿命长，表现出稳定的动力学行为，最终获得了高堆密度(大于0.35g／ml)的球形聚乙烯颗粒；5、本文选择MSPC-5为研究对象，考察了聚合反应参数对催化剂的活性及其聚合物的影响，研究发现：不同的烷基铝对催化剂具有非常重要的影响，特别足TIBA对MSPC-5的助催化活性最高，烷基铝的加入量有一个较佳值，聚合温度为80度时活性最高，H_2的加入使催化剂的活性明显降低且聚合物的分子量也减小；、新型氯化镁载体负载单活性中心催化剂催化乙烯聚合本文创造性采用固体MAO与无水氯化镁直接进行共研磨，制备出了一种的新型的氯化镁载体，并将该载体用于多种单活性中心催化剂的负载化研究，研究表明：1、通过BET、XRD的表征，再次证实了MAO与MgCl_2之间具有直接作用，与XPS的研究结果相一致；2、当研磨时间高于12小时时，延长研磨时间对载体的结构没有显著的影响；3、将配合物3负载于共研磨时间不同的一系列载体上，乙烯聚合结果表明，尽管共研磨时间对负载催化剂的活性具有明显的影响，但是它对聚合物的性能以及催化剂的影响不明显。

Dealcoholization temperature markedly influences the surface area and porosity of the resultant MAO-supports. When the support was pretreated at lower or higher temperature, the corresponding MAO-support shows very low surface area; 2.XRD and IR analyses indicate that MAO has reacted with the residual ethanol in the supports, which is an important manner to get MAO fixed on the carrier. Morever, XPS analyse indicates that MAO can also be coordinated with MgCl_2, which is another way to get MAO fixed on the support; 3.ICP and EDX analyses indicate that dealcoholization temperature not only determined the element content on the solid catalyst, but also influences the element distribution on the carrier; 4.The activities of the supported phenoxy-imine catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature. The support (MSP-5) obtained by treating MgCl_2·2.56C_2H_5OH at 160℃for 4 h, then modified by MAO is very effective for immobilizing complex 3, the resultant solid catalyst (MSPC-5) shows very high activity in ethylene polymerization, and its kinetics of polymerization is stable during the reaction process. Finally, PEs with spherical morphology and high bulk density (over 0.35g/ml) were obtained, without reactor fouling; 5.In this work, polymerization conditions such as alkylaluminums, Al/Zr ratio, temperature and H_2 had a pronounced effect on the activity of MSPC-5 and properties of PE;(3). New MgCl_2-Supported Single-Site Catalysts for Ethylene Polymerization In this work, a kind of new MgCl_2 support was obtained by anhydrous MgCl_2 co-milled with solid MAO, and it is a creative contribution. Then some single-site catalysts were supported on the new MgCl_2 support, and the resulted solid catalysts were tested in ethylene polymerization, the results indicated that: 1.XRD and IR analyses indicate that MAO does be coordinated with MgCl_2, which is in good agreement with the results obtained by XPS; 2.co-mlling time had no obvious effect on the texture of support after 12 hours; 3.In this work, MgCl_2 was co-milled with solid MAO for different hours, and then complex 3 was supported on these co-milled supports. It was found that co-milling time markedly influences the activity of solid catalysts, but it had negligible effect on the kinetic profile and the properties of resultant PE.

XPS研究结果表明，MAO不仅仅只和乙醇作用，MAO还与MgCl_2本身有一定的作用，这是一个极为重要的发现； 3、通过ICP和EDX表征，发现载体的脱醇温度直接影响着元素在固体催化剂中的含量及分布； 4、脱醇温度极大地影响着负载苯氧基亚胺类催化剂的活性和聚合物的性能，特别是原始载体经160℃活化4小时制备得到的固体催化剂MSPC-5的活性明显高于其他脱醇温度条件下制得的固体催化，并且催化剂寿命长，表现出稳定的动力学行为，最终获得了高堆密度(大于0.35g／ml)的球形聚乙烯颗粒； 5、本文选择MSPC-5为研究对象，考察了聚合反应参数对催化剂的活性及其聚合物的影响，研究发现：不同的烷基铝对催化剂具有非常重要的影响，特别足TIBA对MSPC-5的助催化活性最高，烷基铝的加入量有一个较佳值，聚合温度为80度时活性最高，H_2的加入使催化剂的活性明显降低且聚合物的分子量也减小；、新型氯化镁载体负载单活性中心催化剂催化乙烯聚合本文创造性采用固体MAO与无水氯化镁直接进行共研磨，制备出了一种的新型的氯化镁载体，并将该载体用于多种单活性中心催化剂的负载化研究，研究表明： 1、通过BET、XRD的表征，再次证实了MAO与MgCl_2之间具有直接作用，与XPS的研究结果相一致； 2、当研磨时间高于12小时时，延长研磨时间对载体的结构没有显著的影响； 3、将配合物3负载于共研磨时间不同的一系列载体上，乙烯聚合结果表明，尽管共研磨时间对负载催化剂的活性具有明显的影响，但是它对聚合物的性能以及催化剂的影响不明显。

Three kinds of ionic liquid were used to support the acetylacetone at the C3 position directly according to the method indicated above. These synthesized ionic liquid supported acetylacetone catalysts include imidazolium salts ionic liquid supported acetylacetone catalysts, pyridinium salts ionic liquid supported acetylacetone catalysts and ammonium salts ionic liquid supported acetylacetone catalysts. All these catalysts were characterized by ~1H-NMR,~(13)C-NMR, IR and elementary analysis.

采用设计过程中预期能够提高乙酰丙酮金属催化剂催化氧化活性的修饰方式，合成了三类离子液体支载的乙酰丙酮金属催化剂：咪唑型离子液体支载乙酰丙酮金属催化剂、吡啶型离子液体支载乙酰丙酮金属催化剂、胺型离子液体支载乙酰丙酮金属催化剂，并采用核磁共振氢谱、碳谱，红外光谱及元素分析来对这些新型的催化剂进行了表征。

It is demonstrated that the chiral quaternary ammonium salts catalysts exhibit promising catalytic properties for the substrate. Part III: The synthesis and the characterizing of the macroporous aminomethyl resin-supported cinchona alkaloid complexes and the study on its catalytic properties The part consists of two subsections. the macroporous aminomethyl resin -supported cinchona alkaloid complexes were synthesized by the stuff (cinchonine, quinine and macroporous aminomethyl resin). Their structures were characterized by means of elemental analysis, XPS, TG/DTA; the chiral polymer-supported complexes were first used as catalysts for the reduction of ketones. Their catalytic properties for the reduction processes were investigated. The comparison of the products e.e., the conversion of the substrate among different reduction processes was employed with determined by HPLC. The effects of the time, the temperature, the ratio of catalyst to substrate, reaction solvent as well as the recycle times were also discussed.

第三章聚-4-氨甲基苯乙烯负载金鸡纳碱金属络合物的合成与表征及其不对称催化性能研究本章分为两节，以辛可宁和奎宁及聚-4-氨甲基苯乙烯为原料，合成了4种聚-4-氨甲基苯乙烯负载金鸡纳碱络合物催化剂，并对它们的结构用元素分析、X-射线光电子能谱、TG/DTA等几种测试手段进行了表征；首次将所合成的手性高分子负载的金属络合物用于催化芳香酮不对称还原反应，详细研究了所得的手性高分子负载的金属络合物对不同底物的催化性能，用HPLC等分析手段定量检测了还原过程的底物转化率及其产物对映异构体选择性，并考察了反应时间、反应温度、催化剂和底物投料比、反应溶剂和循环次数对催化性能的影响。

Study of Optimization DesignThis paper programs three Command Batch Files that can respectively perform optimization designs of 4-point-supported-glass, 6-point-supported-glass and the specially designed 6-point-supported-glass.

这三段命令流可供熟悉ANSYS操作的工程设计人员使用。

New contributions of this work are as follows:(1). Preparation of Spherical MgCl_2-Supported Late-Transition Metal Catalysts for Ethylene PolymerizationFacile and effective immobilization of late-transition metal catalysts. 2,3-bis-(2,6-diisopropylphenyl) butane diimine nickel dibromide (1) and 2,6-bis-[1-(2,4,6-trimethylphenylimino)ethyl]pyridine iron dichloride (2), for ethylene polymerization has been achieved, using spherical MgCl_2 supports obtained by thermal dealcoholization of MgCl_2·2.56C_2H_5OH, and the effects of dealcoholization temperature on supported late-transition metal catalysts and the properties of resultant polymers were studied, the results indicated that:1.Supports with appropriate mechanical strength, high surface area and high porosity could be prepared by thermal dealcoholization of spherical MgCl_2·2.56C_2H_5OH supports; 2.BET, XRD, IR, SEM, GPC and DSC analyses indicate that the activities of the supported late-transition metal catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature.

本工作的新贡献如下：(1)、球形氯化镁负载后过渡金属催化荆催化乙烯聚合本文将配合物2，3-双(2，6-二异丙基苯亚胺)丁烷二溴化镍(1)和配合物2，6-二[1-(2，4，6-三甲基苯亚胺)乙基]吡啶二氯化铁(2)分别直接负载于经不同热脱醇温度处理的球形氯化镁载体上，研究了氯化镁载体的脱醇温度对负载化后过渡金属催化剂及其聚合物的影响，研究表明：1、通过对球形MgCl_2·2.56C_2H_5OH载体进行热脱醇处理，可以获得合适机械强度、较高比表面积和较高孔隙度的球形氯化镁载体；2、BET，XRD，IR，SEM，GPC和DSC研究表明，脱醇温度极大地影响负载后过渡金属催化剂的活性和聚合物的性能。

New contributions of this work are as follows:(1). Preparation of Spherical MgCl_2-Supported Late-Transition Metal Catalysts for Ethylene Polymerization Facile and effective immobilization of late-transition metal catalysts. 2,3-bis-(2,6-diisopropylphenyl) butane diimine nickel dibromide (1) and 2,6-bis-[1-(2,4,6-trimethylphenylimino)ethyl]pyridine iron dichloride (2), for ethylene polymerization has been achieved, using spherical MgCl_2 supports obtained by thermal dealcoholization of MgCl_2·2.56C_2H_5OH, and the effects of dealcoholization temperature on supported late-transition metal catalysts and the properties of resultant polymers were studied, the results indicated that: 1.Supports with appropriate mechanical strength, high surface area and high porosity could be prepared by thermal dealcoholization of spherical MgCl_2·2.56C_2H_5OH supports; 2.BET, XRD, IR, SEM, GPC and DSC analyses indicate that the activities of the supported late-transition metal catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature.

本工作的新贡献如下：(1)、球形氯化镁负载后过渡金属催化荆催化乙烯聚合本文将配合物2，3-双(2，6-二异丙基苯亚胺)丁烷二溴化镍(1)和配合物2，6-二[1-(2，4，6-三甲基苯亚胺)乙基]吡啶二氯化铁(2)分别直接负载于经不同热脱醇温度处理的球形氯化镁载体上，研究了氯化镁载体的脱醇温度对负载化后过渡金属催化剂及其聚合物的影响，研究表明： 1、通过对球形MgCl_2·2.56C_2H_5OH载体进行热脱醇处理，可以获得合适机械强度、较高比表面积和较高孔隙度的球形氯化镁载体； 2、BET，XRD，IR，SEM，GPC和DSC研究表明，脱醇温度极大地影响负载后过渡金属催化剂的活性和聚合物的性能。

The phylogenetic trees supported that Eriocaulaceae be treated as Eriocaulales because this family always been a nature independent group connected with other families. Eriocaulaceae grouped with Commelinaceae, which supported the close relationship and parallel evolution between the two families. Juncaceae was not close to Eriocaulaceae and more primitive. The relationship between Juncaceae and Cyperaceae was closer than that between Juncaceae and Poaceae. Among these families, Poaceae was the most primitive family and far from Eriocaulaceae. Also in Eriocaulaceae, Eriocaulon was supported to be more primitive.

从构建的系统发育树可以得到：①谷精草科独立形成一个植物类群，支持谷精草科独立成为谷精草目；②谷精草科与鸭跖草科聚成一个大的类群，说明两科的亲缘关系较近，并且表现为平行进化；③灯心草科不近缘于谷精草科，与禾本科相比，灯芯草科与莎草科之间存在更近的亲缘关系；④在进化程度上，灯心草科比谷精草科原始；禾本科与谷精草科的亲缘关系最远，并且在这几个科中处于最原始的进化地位；⑤系统树还支持谷精草科内部的系统关系，支持谷精草属在谷精草科中的原始系统位置。

Treatment of polystyrene-supported selenium ,bromide with lithium acetylides afforded polystyrene-supported selenoacetylene, which reacted with dicyclohexylborane giving a way for stereoselective synthesis of polymer-supported- vinylic selenides .

聚苯乙烯负载硒溴与炔基锂反应合成聚苯乙烯负载炔基硒醚，再与二环己基硼烷反应制得聚苯乙烯负载顺式烯基硒醚；此负载型烯基硒醚在NiCl2(PPh3)2存在下与格氏试剂发生偶联反应，提供了一种有效的-1，2-二取代乙烯的固相有机合成方法

The statistical analysis of this large set of mutations has led us to propose a diagnostic strategy that should help with the molecular work-up of optic neuropathies.

这一大系列基因突变的统计学分析引导我们提出一个诊断策略，可以帮助我们对视神经病变进行分子学的诊断检查。

The results show that the pipe grouting changes the mechanical parameters of surrounding rocks to achieve the security of engineering objectives by reinforcing surrounding rocks and bolcking the water.

研究表明：小导管注浆一方面改变了围岩的力学参数，另一方面利用浆液的固结特性可以实现堵水和加固围岩的工程目标，使隧道在开挖过程中的安全得到保障。