查询词典 pillared

Pillared clay is a kind of the mineral materials, which is synthesized by pillaring inorganic polycations or organic ionic groups into clay minerals. Modified clay is a two-dimensional mineral material with large surface area, high thermal stability, strong surface acidity and variable pore size, therefore it is widely used in such fields as catalyst, sewerage treatment, antibacterial material, photic functional material, ionic conductor, pharmacy, nano-complex preparation and nuclear scrap treatment.

柱撑粘土是矿物材料的一种，它是一种由聚合无机阳离子或有机离子插入粘土矿物中而形成的一种具有二维孔洞的矿物材料，具有比表面积大、热稳定性好、表面酸性强以及孔径可变等特性，因此在催化、污水处理、抗菌材料、光功能材料、离子导体、制药、纳米级复合材料制备、核废料处置等领域有着广阔的应用前景。

Chromia-pillared zirconium phenylphosphonate and phosphate were prepared via preswelling the layered phosphates by ethylamine prior to the intercalation of the pillaring species.

采用乙胺预胶体化方法合成了一系列氧化铬层柱苯膦酸锆和氧化铬层柱磷酸锆催化剂，其铬含量达到22.5%-36.5%，比表面为316-462m^2/g，中孔孔容占总孔容的70%以上，孔径集中在2nm左右。

Based on the above experiments, the author studied the mixed metallic pillared and modified montmorillonites. The experimental result indicated that the microporous structure of Fe-Al-PLMs was affected by the changing of interlayer Fe-Al polymer with different Fe/Al ratio. But the presence of Al iron was helpful to incorporate Fe iron into interlayer of montmorillonites.. Introducing Zr helped Al-PLMs getting better larger spacing, thermal stability, surface area and pore volumes. Its successful to apply Zr-Al-PLMs to treat wastewater containing Cr iron. The experiment of modifying Al-PLMs by PVA showed that the order of adding starting materials (Al-pillaring solution, PVA, montmorillonite solution) was related to the property of Al-PLMs. The PVA as precursor was beneficial for Al to go into interlayer of the clay and to form larger basal spacing porous clay. The surface area and pore volumes of Al-PLMs increased mainly because of increasing the external surface area and mesoporous volumes after acid-activating. This conclusion confirmed that the microporous structure of pillaring clay depends upon the interlayer pillar.

实验结果表明：在Al-PLMs中引入Fe离子，不同Fe／Al比制得的Fe-Al-PLMs因层间的Fe-Al聚合离子结构不同而影响其微孔结构，但羟基Al离子的存在有利于Fe离子进入蒙脱石层间；在Al-PLMs中引入Zr离子，有助于其层间距、比表面积、孔体积增大，所得Zr-Al-PLMs应用于含Cr废水处理效果显著；PVA改性后的Al-PLMs其物化性质变化与铝柱化剂、PVA溶液、蒙脱石溶液三者不同添加顺序有关，说明PVA的前撑有利于Al进入蒙脱石层间得到较大层间距的Al-PLMs；经酸化处理得Al-acid-PLMs，其比表面积增大以外表面积为主，孔体积增大以中孔为主，这也证实了柱撑蒙脱石的微孔结构取决于其层间的柱化物。

As a novel porous material, pillared montmorillonite is one of hotspots for mineral material research. Because of its big surface-to-volume ratio, variable apertures and strong acidity, PILM can be used as an excellent adsorbent and catalyst in petrochemical and environmental protection fields, and catch many scientists attention in recent years.

柱撑蒙脱石作为一种新型的多孔材料是当前矿物材料学研究的热点之一，因其具有大的比表面积、大小可调的孔径、较强的酸性而成为性能优异的吸附剂和催化剂，在石油化工和环保领域具有广阔的应用前景，近年来成为国内外广泛关注和研究的热点。

Two times hydrolyzation of Fe~(3+) and Cr~(3+) was firstly pointed out in the process of pillar preparation with hydrothermal method. In order to improve the thermal stability, Fe/Cr-Si-pillaring agent solution was synthesized by hydrolyzing Fe~(3+) and Cr~(3+) solution on the surface of silica sol, and Fe/Cr-Si-pillared montmorillonite (Fe/Cr-Si-PILM) was prepared with conventional method and hydrothermal method. Because the technical innovation of preparation is the best way to improve the PILM properties, two novel methods (Microwave method and Ultrasonication method) have been studied to synthesize Fe/Cr-PILM.In order to expand PILMs new application in the field of coal conversion, catalytic activity of Fe/Cr-Si-PILM catalyst in LongKou lignite and ShenHua coal residue liquefaction was discussed and characterized in the last part of this paper.

研究证明：蒙脱石的预处理是可行的，我们以预处理后的Ca-M为原料，研究并优化了PILM的水热法制备工艺，提出了金属离子的二次水解法；为了提高PILM的热稳定性，我们自制了硅溶胶，合成了Fe／Cr-Si三元复合柱化剂，并制备了Fe／Cr-Si-PILM；在PILM合成中，制备技术的革新是改进PILM性能的重要方法，为此我们探索了微波合成法和超声波合成法在制备Fe／Cr-PILM中的应用；最后，我们选择龙口褐煤和神华煤液化残渣为研究对象，探索了Fe／Cr-Si-PILM催化剂在煤炭液化中的应用，希望能开拓PILM应用的新领域。

Calcium montmorillonite was prepared by purifying LeXi bentonite with wet method two times. After purification, sodium modification of Ca-M was studied. A series of Fe/Cr-pillared montmorillonites were prepared with conventional method using sodium montmorillonite as experimental materials, and synthesis condition of Fe/Cr-PILM was studied and optimized. In order to shorten the preparation cycle of PILM by overleaping the step of sodium modification of Ca-M, the pretreatment technique for Ca-M has been pointed out for the first time. A series of PILMs were prepared with hydrothermal method using pretreated Ca-M as starting materials, which show that pretreatment of Ca-M is feasible.

然后，本文以莱西膨润土为原料，用二次湿法提纯了-2μm的钙基蒙脱石，对其进行了钠化改型研究；以改型后的钠基蒙脱石为原料，新型的铁、铬复合离子为柱化剂，研究并优化了常规离子交换法制备PILM的工艺；为了简化PILM的制备工艺，我们首次提出了蒙脱石的预处理工艺，希望通过预处理后可以省去蒙脱石的钠化工艺，以Ca-M为原料直接合成PILM。

Keywords tungstenic anion-pillared;LDHs;in-situ synthesis;ion-exchanging

同多钨酸根阴离子；水滑石；原位合成；离子交换

In this thesis, we have developed a new method, i. e., directly impregnating metal salts to uncalcined NH〓〓Si 〓 intercalate of ZrP followed by calcination, to prepare metal oxide supported silica pillared zirconium phosphates with high surface area.

本文采用先负载再焙烧的方法成功地解决了层柱材料负载的问题，制备了大比表面金属氧化物负载的硅柱磷酸锆。

Nickel oxide supported silica-pillared zirconium phosphates with high surface area have been prepared successfully by directly loading Ni〓 to uncalcined APS intercalate of α-ZrP followed by calcination.

1采用将金属盐直接负载到未焙烧的α-ZrP的胺丙基硅脂嵌入物上，然后再焙烧的方法，制备了大比表面负载氧化镍的硅柱磷酸锆。

The climbing fire lit up their faces and threw its ruddy glare upon the pillared tree-trunks of their forest temple, and upon the varnished foliage and festooning vines.

焰腾腾，辉耀着他们的脸庞，也照亮了他们用树干撑起的那座林中圣殿，还把流光镀到那些光滑得似油漆过一般的树叶上和那些缀着花朵的青藤上。

I'm strongly against the death penalty — it's an eye for an eye.

我不赞成死刑——这是以牙还牙的报复行为。

And to get you the support you need, we're enlisting all elements of our national power: our diplomacy and development, our economic might and our moral suasion, so that you and the rest of our military do not bear the burden of our security alone.

并给你们所须的支援，我们正徵召国家所有各种的力量：我们的外交及发展，我们的经济力量与道德劝说，所以你们与其他军人不须要孤独地负起国家安全的责任。