查询词典 optically inactive

From the optically active 2, 2'-dihydroxy-1,1 '-binaphthyl, through esterification, Kumada coupling, bromization, hydrolization and Wittig elimination reaction, 2,2'-diethynyl-1,1'-binaphthyl was obtained.

从光学活性的2，2'-二羟基-1，1'-联萘出发，经过酯化，Kumada偶联，溴化，水解和Wittig消除反应五个步骤，成功地获得了具有单一手性的的2，2'-二乙炔基-1，1'-联萘。

An inclusion complex -BINOL--Omeprazole or -BINOL--Omeprazole was first obtained from racemic omeprazole with chiral host --or --2, 2'- dihydroxy-1, 1'-binaphthyl in high selectivities, and thus both optically pure enantiomers of omeprazole were prepared as syrup with more than 99% enantiomeric excess, the overall yields of both two enantiomers are more than 60%.

首次发现光学纯R--或s--联二萘酚高效识别并包结R--或S--奥美拉唑，形成包结络合物的现象，并首次将包结拆分法应用于手性苯并咪唑类抗溃疡药物的制备，用一种构型的光学纯联二萘酚直接拆分奥美拉唑，可同时得到油状或糖浆状e.e。

Three kinds of optically active pnthalocyanine derivatives modified with chiral 2'-methyoxy-1,1'-binaphthyl; chiral binathyl crown ether; chiral 6,6'-didodecyl- 1,1'-binaphthyl crown ether, have been synthesized and characterized, respectively.

本论文以手性联萘、手性联萘冠醚、冠醚等功能性基团为化学修饰基元，分别合成了三类光学活性酞菁衍生物和两类共轭聚合物，对它们的组装行为以及某些光、电功能性进行了研究。

A series of novel chiral aminophosphine ligands with binaphthyl backbone and partially reduced binaphthyl backbone were synthesized from optically pure NOBIN and H〓-NOBIN respectively. The effects of binaphthyl backbone and substitutes at the phosphorous atom on Pd (0)-catalyzed allylation of racemic 1, 3-dipheylprop-2-en-1-yl acetate with dimethyl malonate were systematically investigated.

从NOBIN出发合成了一系列膦上含有不同取代基的氮膦配体MAPs以及含有被部分还原的联萘骨架的氮膦配体H〓-MAPs，将此两类配体运用于钯催化的乙酸1，3-二苯基烯丙基酯与丙二酸二甲酯的反应中，考查了膦上取代基和配体骨架对反应的影响。

Optically active cyclophane s, such as helical molecules and three-dimensional, cagelike cyclophanes have been the subject of extensive investigation from the standpoints of structural chemistry and material science.

本论文在大量的文献调研和本实验室过去研究结果的基础上，设计了由2，2'-二取代-1，1'-联萘和2，6-二取代吡啶，1，4-二取代苯，4，4'-二取代联苯三种不同连接桥通过炔键链接构筑的拓扑有趣的光学活性环芳化合物-四联萘笼状分子。

X9313U-WS Pinout: The coupler consists of a AlGaAs LED that is optically cou- pled to a dielectrically isolated photodiode array which drives two series connected high voltage MOS transistors.

X9313U-WS引脚说明：该耦合器由一个砷化铝镓发光二极管是光凑发光二极体为介质隔离光电二极管阵列的驱动两个串联的高压MOS晶体管。

Optically active β,δ-dihydroxy esters have been widely used in the synthesis of natural products, polyol fragments, and chiral drugs.

具有光学活性的β，δ-二羟基酯已经在天然产品、多羟基化合物以及手性药物的合成中得到了广泛的运用。

When the readily available homochiral alcohols were used as substrates, highly optically active products 4-vinyl-2-oxazolidinones were easily obtained.

在这个基础上，我们利用手性底物出发进行了手性诱导的反应研究，在两价钯的催化下能够以很好的收率得到光学纯的产物。

From Maxwell's equations, with material constitutive relation of optically active crystal and boundary conditions of electric field on the boundary between isotropic media and crystal, through coordinate transformation, the formula of the direction of refracted wave for arbitrary direction incident monochromic plane wave was derived. Furthermore, based on the unit vector of direction of refracted wave, eigen waves of electric field, electric displacement vectors and direction of energy flow can be easily obtained.

从麦克斯韦方程组出发，结合旋光晶体的物质方程以及单色平面波从各向同性介质入射到晶体界面时电场的连续性边界条件，通过晶体主轴坐标系和界面坐标系的坐标变换，推导了任意入射方向的单色平面波在晶体界面上的折射方向的求解公式，进而利用所得的折射方向求解晶体中折射波的电场本征模、电位移矢量本征模和光线方向。

We examined the reduction of COBE to optically pure-CHBE by E. coli transformants in a water monophase system reaction and discuss the possible use of this type of reaction system in industrial applications.

我们研究ㄋ在水单相体系中由COBE还原生成纯光学旳CHBE，还讨论ㄋ这种反应体系在工业应用中可能旳用途。

Who? I never heard of him, Paul said, before asking teammate James Posey if he had heard of him.

赛后，科比说，他一直都是一名非常出色的射手，今天他打得很棒。

When I joined the company, I rotated around the different sections.

我加入这个公司时，轮换过几个不同的部门。