查询词典 Chain Reaction

The photo decomposition reaction of lead styphnate is a simple thermal decomposition reaction, in which light energy rise will increase the rate of decomposition reaction of lead styphnate and the decomposition reaction has clear stages at higher light energy.

激光束能量增大能明显地提高斯蒂醋酸铅的分解反应速率，而且在较高的光能量下，分解反应出现明显的阶段性。

The optimal reaction conditions were as follows:chloroform was used as the reaction solvent,3,5-propionyl acid 0.02 mol,sulphoxide diloride 0.054 mol,the reaction temperature 50℃ and the reaction time 5 h. Under these conditions,the yield of product was 98.9%.

对酰氯合成条件进行了研究，得出优惠反应条件为：以氯仿作溶剂、β-（3，5-二叔丁基-4-羟基苯基）丙酸0.02 mol、二氯亚砜0.054 mol、反应温度50℃、反应时间5 h，优惠条件下产品的收率为98.9％。

The phosphorus oxychloride or phosphorus tribromide N, N-dimethylformamide mix and react to form the Vilsmeier reagent used in the reaction. The newly prepared Vilsmeier reagent is added into the reaction bottle provided with the return condenser and the blender; a reaction raw material N, N-dimethylformamide solution expressed in the reaction formula is added into the system; the temperature is risen; the corresponding multi substituting pyridine-2 (1 H)-ketone compound can be made after the column chromatography of the silica gel; the production rate is between 60 and 95 percent according to different reactions.

由三氯氧磷或三溴化磷N，N-二甲基甲酰胺混合获得反应中所用Vilsmeier试剂；将新配制的Vilsmeier试剂加入装有回流冷凝管、搅拌器的反应瓶中，向体系中加入反应通式中表示的一种反应原料的N，N-二甲基甲酰胺溶液，升温，经硅胶柱层析分离得相应的多取代吡啶-2(1H)-酮类化合物，产率视不同反应在60~95％之间。

Moreover, the kinetics of the esterifieation reaction using ammonium molybdate as catalyst was studied. The result showed that the reaction was chemical reaction controlling. The rate equations were established, and the reaction models gave satisfactory result.

对钼酸铵为催化剂时2，6-NDCA甲酯化反应动力学进行了研究，结果表明，该反应属化学反应控制，根据实验结果，建立了反应的宏观动力学方程式，动力学模型有较好的拟合效果。

The effect of reaction temperature,reaction time,materials ratio on the synthesis of piperidine alcohol benzoate ,hindered amine light stabilizer,from piperidine alcohol and benzoyl chloride by direct condensation were studied,and the proper technological conditions were given as follows:the reaction temperature is 95℃;reaction time is 4 h; the mole ratio of reactants,n∶n is 1∶1.4,the amounts of solvent is 40 mL(based 0.1mol piperidine alcohol),the arerage yield ...

王树清，高崇，苯甲酸哌啶醇酯HALS的合成工艺研究研究了以苯甲酰氯和哌啶醇为原料直接缩合合成苯甲酸哌啶醇酯受阻胺光稳定剂时反应温度、反应时间、原料配比等条件对合成反应的影响，确定了最佳工艺条件。最适宜的工艺条件是：反应温度95℃、反应时间6h、原料摩尔比n∶n为1∶1.4，溶剂用量为70mL(相对于0.1mol哌啶醇)，苯甲酸哌啶醇酯的收率为91.05%，产品纯度98.5%。

There are three different nucleophilic reagent respectively reaction with m-dinitrobenzene ramification at distint alkaline term:With the nitrobenzene 、 m-nirtobenzenesulfone sodium salt 、 2.4-dinitro chlorobenzene 、 m-dinitrobenzene for bottom thing, benzyl cyanide、 benzyl chloride、 benzyl chloropyridine、is a nucleophilic reagent reaction for under the different term proceeds a series reaction. At the same time ,discuss about the impact factor to nucleophilicity such as the number of attract electron group、 ability of attract electron and the nucleophilic substitution reaction part.

设计了三类不同的亲核试剂分别与活化芳环在不同的碱性条件下发生反应：以苄基氰、苄基氯化吡啶为亲核试剂，以硝基苯、间二硝基苯、间硝基苯磺酸钠、2，4-二硝基苄基氯为底物进行亲核取代反应；并且对亲核试剂的体积效应、溶剂效应对亲核性影响，底物上吸电子基团的数目、吸电子能力对亲电性的影响，以及亲核取代反应的发生部位受哪些因素影响进行探讨。

The experiments for determining the reaction kinetics of Daqing atmospheric residue were performed in a continuous flow, expanded bed rector. Four-lumped reaction kinetic model was developed to account for various feed and product fractions of Daqing atmospheric residue (gases, gas oil, residue and coke). The amounts of olefins and alkyls in the gas products were further analyzed to determine reaction kinetics of gas product distributions. Hence, a combined five-lumped reaction kinetic model was obtained for catalytic pyrolysis of Daqing atmospheric residue. The kinetic constants both in four-lump model and five-lump model were evaluated. A simulator for catalytic pyrolysis process was developed by incorporating the five-lumped kinetic model into the hydrodynamic flow model.

其次利用改进的固定流化床装置考察大庆常压渣油催化裂解反应规律，筛选反应工艺参数；分析了催化裂解工艺存在的主要化学反应类型，提出了渣油一次反应和二次反应网络图；将反应原料油作为单独集总组分，而将产品中的轻质油、气体、焦炭分别作为集总，从而建立了四集总动力学模型；在此基础上，把气体产物中的目的产物低碳烯烃独立划分，得到五集总动力学模型；采用最小二乘法分析实验数据，分别得到四集总动力学模型和五集总动力学模型中各集总间相互反应转化的反应速率常数。

The traditional technology of iron carbide production exists the problem that the reaction time is too long. The research of adding the additive into the ore of the fluid-bed was carried out in order to find the catalyst of this reaction. It was found out that K2CO3 and CaCl2 can be the catalysts of this reaction. The reacting time and equilibrium data in addition of K2CO3 and CaCl2 were examined and were campared with the contrastive experimental results respectively. The theoretical dynamics analysis also reveals that both K2CO3 and CaCl2 can accelerate the iron carbide forming reaction.

摘 要：传统的碳化铁生产工艺存在反应时间较长的难题，为此通过在流化床入炉矿石中配加部分添加剂的还原实验研究，以寻求该反应可能的催化剂，缩短反应时间，提高碳化铁生产效率和经济效益采用CaCl2和K2CO3作为反应的催化剂，利用反应所测数据，与对比实验相比较，并结合动力学分析，得出CaCl2和K2CO3可以加速碳化铁还原反应进行的结论。

The result shows that the elimination reaction and ring closing reaction are synergistic, and the hydrogen in the elimination reaction derives from hydroxyl. In addition, the activation energy of the reaction is 139.2kJ/mol.

计算结果表明，该反应中的消除反应和成环反应是协同进行的，溴化氢消除反应中的氢来自与O(22)相连的羟基氢，反应的活化势垒为139.2kJ/mol，反应放热25.1kJ/mol。

The non-isothermal decomposition kinetics of nylon 1010 and nylon 1010/POSS composites in nitrogen were investigated. POSS significantly increased the activation energy but had little effect on the reaction order.(5) Exploring research was carried out on the reaction between EVM and nylon 1010. The reaction between EVM and TsOH during melt mixing was also invesigated, and related reaction mechanisms were studied in terms of NMR, TGA-FTIR and etc.

五初步研究了乙烯-醋酸乙烯酯橡胶和尼龙1010在高温下的反应性，报道了EVM和TsOH在高温条件下的反应性，通过核磁共振、热重-红外联用等分析表征方法探索了相关的反应机理，EVM和TsOH反应后，EVM的耐溶剂性、玻璃化转变温度和力学性能均有所提高，而体积电阻率则显著下降。

The system can be widely used in belt weighing and batching process control,etc.

介绍了基于智能模糊控制的嵌入式配料系统的设计方法，对模糊PID控制过程和系统调零作了重点的讨论，同时给出了PID控制的程序流程图和系统定长调零子程序。

"I dunno," she answered,"but if you show me aroun', I'll recognize it from the lighthouse just outside the porthole."

"我不知道，"她回答说，"如果你能带我转转，我能认出来的，因为灯塔就在舷窗外。"