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In the reforming operation a light hydrocarbon feed isomerizes on contact with a suitable catalyst to produce gasoline with a higher octane number.
在重整操作中，一个轻质烃类进料与一个合适的催化剂接触而异构化得到具有高辛烷值的汽油。
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The results show that this reaction proceeds in two step: 1 silylene and formaldehyde form an intermediate complex, which is a kind of exothermal reaction with no barrier; 2 the intermediate complex isomerizes to sive the product. The barrier for the second step is 51.4kJ·mol^-^1 at MP2/6-31G^*//6-31G^* level (with zero-point energies correction). In view of dynamics and thermodynamics, it is between 300～400K that the reaction will have not only larger spontaneous tendency and equilibrium constant but also quicker reaction rate.
结果表明，此反应历程由两步组成：1硅烯与甲醛生成一中间配合物，是一无势垒的放热反应，2中间配合物异构化为产物，此步势垒经零点能校正后只有51.4kJ·mol^-^1(MP2/6-31G^*//6-31G^*)；从热力学和动力学的综合角度考虑，该反应在300～400K温度下进行为宜，如此，反应既有较大的自发趋势和平衡常数，又具有较快的反应速率。
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Carbon cations are important organic reaction intermediates,and hydrogen shift is a key path through which carbon cations isomerizes.
正碳离子是重要的有机化学反应中间产物，而氢原子移位则是正碳离子异构化的主要反应途径。
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dynamic isomerizes：动态异构体
dynamic isomerism || 动态异构现象 | dynamic isomerizes || 动态异构体 | dynamic laser || 动态激光器,气动激光器