查询词典 negative complex

The metal ions of the dinuclear copper complex of [Cu_2_2Cl_4] are linked by two N~1,N~2 1,2,4-triazole bridges,and the central Cu ions have distorted trigonal bipyramid geometries. The central Cu ion of [CuL22]·H2O has a centrosymmetric and distorted tetragonal-octahedral geometry. The metal ions of the dinuclear manganese complex of [Mn_2L_2_2Cl_2(H_2O)_2] are bridged by two chlorine atoms, and the central Mn ions have distorted tetragonal-octahedral geometries. Part III.

配合物[Cu_2_2Cl_4]是通过配体L的1，2，4-三唑环上两个氮原子(N~1，N~2)桥联形成的双桥双核配合物，每个中心铜离子都具有畸变的三角双锥构型；配合物[CuL22]·H_2O的中心铜离子具有中心对称的畸变八面体构型；配合物[Mn2L2_2Cl_2(H_2O)2]是通过两个氯原子桥联形成的双桥双核配合物，每个中心锰离子都具有畸变的八面体构型。

The crystal structures of two complexes have been determined by X-ray diffraction as: complex (11) is distorted octahedron configuration,α=15. 9002 (6), b=16. 2413 (5), c=23. 4401 (8)〓,β=90°, V=6053. 2 (4)〓, Z=8 and R=0.0531; complex (8) is trigonal bipyramidal configuration,α=9. 3476 (8), b=17. 4236 (13), c=9. 7836 (8)〓,β=91. 197 (3)°, V=1593. 1 (2)〓, Z=2 and R=0.0325, which shows that three secondary amine groups (N-1, N-2, N-3) of the glycosylamine ligand forms the equatorial plane, and the tertiary amine (N-4) and one Cl〓 are pointed on the apical positions.

分别对其进行X-ray衍射分析可以得出：配合物(11)的晶体数据为α=15.9002(6)，b=16.2413(5)，c=23.4401(8)〓，β=90°，V=6053.2(4)〓，Z=8 and R=0.0531，为畸变的八面体构型，而配合物(8)中，α=9.3476(8)，b=17.4236(13)，c=9.7836(8)〓，β=91.197(3)°，V=1593.1(2)〓，Z=2 andR=0.0325，为三角双锥构型，糖胺配体的三个氮原子（N-1，N-2，N-3）位于赤道平面上，而另外一个氮原子（N-4）和一个Cl〓位于轴向上。

Result showed that tetrasubstituted calix [4] arenes in lower rim were stronger complex abilities than bisubstituted calix [4] arene with transition metal, heavy metal and rare earth ions. But when introducing the aminephenolicalcohols in the 1, 3-bisubstituted calix [4] arenes, the complex abilities were improved.

结果表明：在Lower rim上四取代的杯[4]芳烃配体比1，3-二取代的杯[4]芳烃配体对过渡金属离子，重金属离子及稀土离子有更好的配位能力，但当1，3-二取代的取代基上引入醇胺链型配体时，对金属离子也有很好的配位能力。

Resonance light scattering spectrum of cadmium- phenanthorline- bromophenol blue system has been studied. The effects of interference substances and optimization of procedure have been investigated. In the presence of Tris-HCl(pH=9.60),Cd2+ reacts with Phen to form the chelate cation, which further reacts with acid dye of BPB to form an ion-associated complex. Then, the complex molecules are accumulated to particles by virtue of hydrophobic forces and other molecular forces. This results in significant enhancement of RLS intensity, and the enhanced intensity of RLS at 638nm is proportional to the concentration of Cd~(2+).

研究了镉-邻菲罗啉-溴酚蓝体系在碱性条件下的共振光散射光谱特征，考察了体系的影响因素和最佳反应条件，研究表明，在pH=9.60的Tris-HCl介质中，镉与邻菲罗啉形成络阳离子，再与酸性染料溴酚蓝形成离子缔合配合物，在疏水力等分子间作用力下，缔合物分子聚集形成缔合微粒，溶液的共振散射光显著增强；在638nm处RLS增强程度与镉浓度成线性关系，线性范围为0-3.20mg/L，检出限为4.50ug/L。

This paper has done a deeply research on the evaluative method, which focus on maintaining and ensuring the camion. After deeply analyzing the maintain theory of army equipment and the stratagem 's characteristic and combining the current systems engineering evaluating theories and methods, it has analyzed and solved all limitations that coming forth when a single model is used to evaluate the maintain capacity. After analyzing and ameliorating the judgment of AHP's coherence, the calculation of the expert power value and the optimizing of the more-extreme judging model, a new calculation method, the multidimensional complex calculation theory, is presented, which much fits for the evaluative calculation of the camion. The new theory's feasibility and the evaluation's reliability have been proved in theory in this paper. This paper also analyses the principle and the program, which is about building a camion evaluating system. According to the multidimensional complex calculation theory, an evaluative model has been built. Applying the levels analytical method, this paper fixes on the calculation of every target's power, brings the optimization allot precept of macro spatial resource, optimizes the resource of the maintainability of theater of operations' vehicle, which offers a theory foundation for optimizing of the resource space. The research not only brings out a uniform standard for the evaluating of the maintain ability of the camion, but also presents a theory foundation and method for perfecting the camion maintain system.

本文对军用车辆维修保障能力评估的方法论进行了深入研究，在理论上通过对军事装备维修理论及战略特性的深入剖析，结合现有系统工程评估理论、评估方法的特点，分析解决了应用单一模型评估装备维修能力问题的各种缺陷，就AHP法判断矩阵一致性判定，群策专家权重值的确认及多元评判模型的优化进行了研究和改进，形成了适应军事车辆维修保障能力评估应用的新算法--多元复合算法理论，对这一创新评价理论的科学性及评估可靠性进行了理论证明和算法应用；研究分析了建立军用汽车维修保障能力评估指标体系的原则和程序，并按照多元复合算法的理论，建立了车辆维修保障能力评估模型；应用层次分析法的原理，明确了各指标权重的算法，提出了宏观空间维修资源优化分配方案，优化了战区车辆装备维修能力资源空间，为某一具体车辆装备维修能力形成所需维修资源空间的优化提供了理论依据；本文的研究既为军用车辆装备维修保障能力评估提供了统一的衡量标准，也为军事装备维修保障系统的进一步完善提供了理论依据及方法手段。

A novel solid complex of gelatin hydrolysate and cerous chloride was synthesized successfully,and the complex reaction between gelatin hydrolysate and rare earth cerium was verified by FT-IR.

以工业明胶为原料，选用优质的肽键断裂剂，通过优化设计实验方案，确定最佳的实验条件(温度、水解时间、pH值)，试制出合格的水解明胶。

In the buffer solution of HAc-NaAc at pH 3.5, Cr reacts with chrysin by molar ratio 1:3, and forms a highly fluorescent active complex in the presence of some methanol. The maximum excitation and emission wavelengths of the complex are 260 nm and 429 nm respectively.

在含一定量甲醇的pH=3.5的HAc-NaAc缓冲溶液中，铬与白杨素能形成1：3的二元荧光配合物，其最大激发波长和发射波长分别为260 nm和429 nm。

The Liushuigou intermediate-basic meta-igneous complex at Guanzizhen, Tianshui, is composed mainly of metagabbro-metagabbro diorite-metadiorite, and the Baihua basic meta-igneous complex consists mainly of pyroxenite-gabbro-diorite-quartz diorite. They form a relatively complete comagmatic evolutionary series.

提要：天水地区关子镇流水沟变质中基性岩浆杂岩主要由变质辉长岩—辉长闪长岩—闪长岩组成，百花变质岩浆杂岩主要由辉石岩—辉长岩—闪长岩—石英闪长岩组成，构成较完整的同源岩浆演化序列。

The inhibition level by daphnetin for 1, 2, 3 and 4 h were 7%, 51%, 69% and 75% respectively, while the values treated by daphnetin-Fe complex were 8%, 6%, 11% and 9% respectively. The inhibition level by daphnetin at different concentrations （0.1, 1, 100 and 1 mmol/L） for 6 h was 3%, 31%, 58% and 93% respectively and while the values treated by daphnetin-Fe complex were 8%, 6%, 11% and 9%.

经瑞香素（100 μmol/L）作用1、2、3和4 h后RNR活性分别被抑制7%、51%、69%和75%；在瑞香素浓度为0.1、1、100和1 000 μmol/L，作用6 h后，RNR活性分别被抑制3%、31%、58%和93%；而瑞香素-Fe复合物作用6 h后RNR活性分别被抑制8%、6%、11%和9%。

Dealcoholization temperature markedly influences the surface area and porosity of the resultant MAO-supports. When the support was pretreated at lower or higher temperature, the corresponding MAO-support shows very low surface area;2.XRD and IR analyses indicate that MAO has reacted with the residual ethanol in the supports, which is an important manner to get MAO fixed on the carrier. Morever, XPS analyse indicates that MAO can also be coordinated with MgCl_2, which is another way to get MAO fixed on the support;3.ICP and EDX analyses indicate that dealcoholization temperature not only determined the element content on the solid catalyst, but also influences the element distribution on the carrier;4.The activities of the supported phenoxy-imine catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature. The support (MSP-5) obtained by treating MgCl_2·2.56C_2H_5OH at 160℃for 4 h, then modified by MAO is very effective for immobilizing complex 3, the resultant solid catalyst (MSPC-5) shows very high activity in ethylene polymerization, and its kinetics of polymerization is stable during the reaction process. Finally, PEs with spherical morphology and high bulk density (over 0.35g/ml) were obtained, without reactor fouling;5.In this work, polymerization conditions such as alkylaluminums, Al/Zr ratio, temperature and H_2 had a pronounced effect on the activity of MSPC-5 and properties of PE;(3). New MgCl_2-Supported Single-Site Catalysts for Ethylene PolymerizationIn this work, a kind of new MgCl_2 support was obtained by anhydrous MgCl_2 co-milled with solid MAO, and it is a creative contribution. Then some single-site catalysts were supported on the new MgCl_2 support, and the resulted solid catalysts were tested in ethylene polymerization, the results indicated that:1.XRD and IR analyses indicate that MAO does be coordinated with MgCl_2, which is in good agreement with the results obtained by XPS;2.co-mlling time had no obvious effect on the texture of support after 12 hours;3.In this work, MgCl_2 was co-milled with solid MAO for different hours, and then complex 3 was supported on these co-milled supports. It was found that co-milling time markedly influences the activity of solid catalysts, but it had negligible effect on the kinetic profile and the properties of resultant PE.

XPS研究结果表明，MAO不仅仅只和乙醇作用，MAO还与MgCl_2本身有一定的作用，这是一个极为重要的发现；3、通过ICP和EDX表征，发现载体的脱醇温度直接影响着元素在固体催化剂中的含量及分布；4、脱醇温度极大地影响着负载苯氧基亚胺类催化剂的活性和聚合物的性能，特别是原始载体经160℃活化4小时制备得到的固体催化剂MSPC-5的活性明显高于其他脱醇温度条件下制得的固体催化，并且催化剂寿命长，表现出稳定的动力学行为，最终获得了高堆密度(大于0.35g／ml)的球形聚乙烯颗粒；5、本文选择MSPC-5为研究对象，考察了聚合反应参数对催化剂的活性及其聚合物的影响，研究发现：不同的烷基铝对催化剂具有非常重要的影响，特别足TIBA对MSPC-5的助催化活性最高，烷基铝的加入量有一个较佳值，聚合温度为80度时活性最高，H_2的加入使催化剂的活性明显降低且聚合物的分子量也减小；、新型氯化镁载体负载单活性中心催化剂催化乙烯聚合本文创造性采用固体MAO与无水氯化镁直接进行共研磨，制备出了一种的新型的氯化镁载体，并将该载体用于多种单活性中心催化剂的负载化研究，研究表明：1、通过BET、XRD的表征，再次证实了MAO与MgCl_2之间具有直接作用，与XPS的研究结果相一致；2、当研磨时间高于12小时时，延长研磨时间对载体的结构没有显著的影响；3、将配合物3负载于共研磨时间不同的一系列载体上，乙烯聚合结果表明，尽管共研磨时间对负载催化剂的活性具有明显的影响，但是它对聚合物的性能以及催化剂的影响不明显。

Chinese traditional virtue is humility and wariness,the compliment and praise to the others should be declination

中国人的传统美德是谦虚谨慎，对别人的恭维和夸奖应是推辞。如

We bought this house on the never-never.

我们以分期付款的方式买下这座房子。