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The chelate structure was examined by AFM scaning, single strand structure at AFM gram is Ala-Gln, two combined single strand is Ala-Gln-Zn~(2+), and atomic radius of Ala-Gln-Zn~(2+)'s conjunctive atom is about 0.24 to 0.25nm, which is near to Zn~(2+), so the conjunction atom is Zn~(2+). Thus the coordination reaction and the molar ratio 2:1 is proved again.

原子力显微扫描指出,大量出现的单一弯曲链状结构是Ala-Gln分子,而两两组合连接的链状结构,则是Ala-Gln-Zn~(2+)螯合物,且连接两个链状结构、半径约为0.25nm的中心原子是Zn~(2+),证明Ala-Gln与Zn~(2+)形成配位比为2:1稳定螯合物。

The X-ray crystal structure reveals that thiourea coordinates with Pd via S atom,and the complex as a whole was in complete symmetry with palladium atom at the symmetry center of the plane square structure.

硫脲是有效反萃剂,从萃合物的晶体结构看出,硫脲通过S原子与Pd配位,萃合物以Pd原子为中心构成平面正方型结构。

The integrated analytical results show that the novel ligand coexists in ketoform and enolform structures under the measuring conditions, the ketoform structure may change into the enolform structure during the coordination and bonds with the central ion by two O atoms of the enolized hydroxyl group of pyrazolone ring and H2O and the N atom of the imine group and the N atom containing H of benzimidazole ring by losing the proton. And the coordination number of these complexes is four.

综合各种分析结果显示:配体在测试条件下以酮式和烯醇式结构共存,配位时酮式可能转化为烯醇式结构,按去质子的方式以吡唑啉酮环羟基和H2O上的两个O原子以及亚胺基上的N原子和苯并咪唑环上的含氢N原子与中心离子成键,配合物的配位数为4。

It is found that in this structure the molybdenum atom is coordinated by six sulfur atoms of three 1, 1 -dicynoethylene 2 ,2 -dithiolate(i-mnt2 -) ligands and a terminal oxygen atom, forming a distorted pentagonal bipyramidal structure.

结构分析结果说明Mo原子与三个配位基的六个硫原子和一个端基氧形成扭歪五角双锥结构。

The structure of the compound 〓(1) consists of a pentanuclear molecule which is center-symmetric. One W atom is coordinated by four S atoms and two Cu atom. As expected, the Fe atoms are sandwiched between two staggered pentadiene rings. The most interesting aspect of the structure is that Fe-C-P-Cu-P-Cconstitutes a distorted hexagon and Fe-Cu-W-Cu-Fe is nearly in a line.

结构是以W原子为对称中心含有五个金属原子的线型结构,W原子与四个μ〓-S和两个Cu原子配位;Fe原子在两个戊二烯环中间形成一个三明治夹心结构;Fe〓-C〓-P〓-Cu〓-P〓-C〓-构成扭曲的六边形,由于两边1,1'-双二茂铁配体的作用导致Cu-S键的拉长。

The quality of interior environment in nursing home residents will become one of the attention-getting subjects due to the gradual increase of aging populations This paper directs at the research of nursing home's interior environment factors in Tainan We use the standard of international practice to analyze the intrinsical data of environmental monitoring and establish the characteristics which from environmental physical reaction of nursing home The research items are air environments (PM10 CO CO2 formaldehyde TVOC) temperate environments and light environment (illumination average brightness daylight factor) etc There are the inductive conclusions of this research: 1 In basic medicine the clinical diagnosis means the theory and technique about physical examination with patients The definition of clinical diagnosis in architecture should be the diagnosis of building preserve and improve the feasible way to extend building's service life and assure the residents of the healthy quality of interior environment The object of clinical diagnosis in architecture is not only to ensure the use of structure and environment quality but also keep the structure and environment quality in sustainable; therefore creating an efficient system of preserving plan is needed 2 It is an accurate and technical circumstance which about improving remedying and reconstructing the problems of structure space This circumstance includes finding questions ensuring causation ascertaining ultimate strength evaluating environment quality estimating the necessary of restoration and implementing on a suitable way Furthermore when reconstructing and ameliorating the appearance of structure space it should be respected and the memories of it should be preserved 3 In clinical diagnosis of environment quality of space the question of physical environment and the deficiencies of structure must be separated The structure space of construction and the high quality of space should be inspected strictly then observed the crucial reason that can find out any invisible and hidden causes The diagnosis of construction is to observe the reason of destroyed structure The environmental diagnosis of indoor and outdoor is to find out the crucial reason that influences health 4 In order to decrease the iterant problems the construction and environment of space should be diagnosed However the destruction by natural strength and artificial using by human are important causes that can affect the service life of construction Searching the cause of disease just like curing the patient which includes inspection diagnosis cure and prevention We tested the thermal conductivity of siding material in this research and then found out the roof east vertical face and west vertical face have most radiant heat especially the construction of RC The characteristics of opaquely outer casing have relations with the thermal conductivity of wall to wiz the ability of heat insulation Therefore increasing the efficiency of heat insulation and decreasing the endoergic factor of insolation are very important to temperate environments

而随著国内老年人人口逐渐增加,逐渐迈向高龄化之同时,对於高龄者使用空间之室内环境品质相关议题之探讨,亦成为未来我们需加以关注之议题之一。主要为针对台南某安养中心室内环境因子进行检测调查工作,利用现场室内环境测定以取得有效的实测数据;再藉由汇整相关国际评估基准,并进行实测数据比对分析,建立老人安养中心对物理环境反应之特性。并以前期相关研究文献回顾与老人安养中心实测案例现场的实验,来了解不同空间物理环境特性之影响,并将结果回馈实际建筑及室内设计之用。调查工作项目包含:空气环境之PM10、CO、CO2、甲醛、TVOC;温热环境之室内温度、相对湿度、人体PMV、PPD;光环境之照度、均齐度、昼光率等因子调查。本研究结果可归纳以下几点结论: 1 所谓临床诊断医学乃相对於基础医学而言,是指实际与病人接触的医疗及护理行为中牵涉到的理论和技术;而建筑的临床诊断的定义应为建筑本体与室内外诊断、维护及改善所有可行的方式来延长建筑物的寿命,并确保人与室内环境空间品质的健康。建筑临床诊断目的为确保结构体与环境品质能继续使用,而能维持所需要的效能及承受能力。一个有效的维护计画体系是必须建立的 2 在建筑空间之问题改善、治疗与修复执行中,是一个精确与技术性的事项,其中包含找出问题、确定原因、评估结构应力强度、评估环境品质、评估修复与改善必要性、选择及执行一个适当的过程。其改善与修复也必须尊重建筑空间原有色彩与形貌,并保留原有记忆及文化。 3 在临床诊断中空间环境品质中,物理性环境问题与结构构件缺陷必须分别判断,诊断建筑空间之结构与空间舒适品质必须详细观察其症结性问题,才能发现任何隐藏及有潜伏性缺陷的原因。建筑本体诊断是观察出建筑本体之破坏原因,而是内外空间环境诊断目的在於的找出影响健康因素之症结性问题。 4 建筑本体与空间环境之预防评估目的为降低与抑制问题的再发生。然而,自然力的破坏与人为使用因素皆是影响建筑生命期之主要因素,找出病源问题就如同医生对病人的处理,包含了侦查、诊断、治疗以及预防。 5 本研究以外墙材料热传导率测试结果发现,屋面与东西向立面是承受辐射热最多的地方,尤以 RC 的建筑更甚,不透明部分的外壳能特性主要与壁体的热传透率即隔热能力有关,但是承受来自日射的吸热影响,因此增加隔热性能与降低日射吸热因子是对温热环境是非常重要的。

Five novel torsion-mirror optical actuators including double-beam thickness differential structure with single torsional axis, double flexible folded-beam structure with single torsional axis, double-beam vertical torsion comb structure with single torsion axis, four-beam differential compound-micromirror structure with double torsional axis and the combined structure of the four basis forms above, are brought forward. All of these devices could be fabricated by the same silicon micromachining process we have developed. The deformation compensation design with local enhancement for the thin torsional beam which is the key structure of these devices is also put forward to improve the reliability. The three-dimension solid model and two-dimension reduced order model of the torsion-mirror optical actuator are established and then the numerical simulations for evaluating the device characteristics of the statics, dynamics, electrostatic field, mechanical and electrostatic coupling, fluid and solid coupling are carried out to optimize the structure design. Furthermore, three optical fibre clamping structures which could be integrated monolithicly are designed and analyzed to improve the optical coupling capability. 4. Three flexible process flows combined with bulk silicon micromachining and surface silicon micromachining are brought forward to fabricate these novel single-crystal silicon or polysilicon torsion-mirror optical actuators by using the same lithography masks for both SOI wafer and regular silicon wafer. A series of important process experiments are carried out to optimize the process parameters and the process flows. Some novel and typical process phenomena which occurred during the microfabrication are analyzed and then the corresponding solutions are put forward. 5. A MEMS dynamic testing system which exploit blur image synthetic technique, stroboscopic image matching technique, stroboscopic mirau microscopic interferometry technique and microscopic laser dopper vibrometer technique is set up to measure three-dimension and six-freedom micro motions of any MEMS devices with nanometer resolution.

在对硅微机械扭转镜光致动器的光机电特性系统地理论研究的基础上提出了硅微机械扭转镜光致动器的结构设计准则。3、提出了单轴双梁厚度差分结构、单轴双柔性折叠梁结构、单轴双梁垂直扭转梳齿结构、双轴四梁差动复合微镜结构以及以上四种基本结构组合后的衍生结构等五种工艺加工技术兼容的新型的硅微机械扭转镜光致动器,对器件关键结构薄厚度、高耐疲劳扭转梁进行了局部加强的变形补偿设计,建立了器件的三维实体模型以及两维降阶模型,对提出的新结构硅微机械扭转镜光致动器进行了系统的静力学、动力学、静电场、力电耦合和流体固体耦合的建模仿真与优化设计,同时设计并分析了三种可实现单芯片集成的弹性光纤定位夹紧结构。4、提出了组合体硅微加工技术与表面硅微加工技术、兼容同一套光刻版图、可分别基于SOI 晶片和普通Si 晶片、适应于制造提出的各种新结构单晶硅和多晶硅硅微机械扭转镜光致动器的三套柔性加工工艺流程,开展了一系列重要工艺步骤的单项工艺试验,对工艺流程与工艺参数进行了优化,针对加工过程中出现的具有普遍意义的典型工艺问题进行了讨论和分析,并提出了解决方法。5、创新性地将模糊图像合成技术、频闪图像匹配技术、频闪Mirau 显微干涉技术与显微激光多普勒测振技术有机结合,建立起了一套周期运动测量与瞬态运动测量相结合、单点运动测量与全视场运动测量相结合、满足不同MEMS 器件各种动态测试要求的集成的MEMS 三维六自由度微运动精密测量系统。

According to core observation and description, many deformation structures with seismite characteristics are recognized within sandstone and shale sedimentary strata of Paleogene continental faulted basin in Yangxin Subsag, such as micro-faults, earthquake fissures, liquefaction sandstone veins, water-escape structure, vibrational liquefaction deformation structure, seismic pillow structure and associated structure, etc. The vertical sequence of seismites in Yangxin Subsag, in ascending order, is underlying unshocked layer, micro-faults layer, autoclastic shattered breccia layer, vibrational liquefaction deformation structure layer, seismic pillow structure and associated structure layer, liquefied homogeneous layer and overlying unshocked layer, which corresponds to different earthquake intensity respectively.

通过岩心观察和描述,在阳信洼陷古近系陆源碎屑断陷湖盆砂泥质沉积地层中识别出大量具有震积岩特征的变形构造,如微断层和震裂缝、水下岩脉和泄水构造、振动液化卷曲变形构造、震积枕状层及伴生构造等,同时建立了阳信洼陷震积岩垂向序列,自下而上分别是下伏未震层段、微断层层段、震碎角砾岩段、振动液化卷曲变形层段、震积砂枕及伴生构造层段、液化均一层段和上覆未震层段。

The social level structure is defined from its basic conception, in-depth meaning and characteristics. The term refers to a functional being and social reality, a unity of physical space and value space as well as connectional and theoretical existence. Viewed from the perspective of political philosophy, the social level structure is a political sovereignty grading or ladder in a state who values the supremacy of sovereignty, penetrating into economic, cultural and social fields, universally forming social relationship. Based on general social structure, social system and political sovereignty, the social level structure is an abstractly summary of social hierarchy which is neither a copy of political structure nor simply addition of economic, cultural and social structure. The social level structure is long hidden but universally existing, deeply affecting and shaping social system, people's life and thinking. Based on the above, the thesis probes the social foundation, evolutional law, fundamental quality, running mechanism, historical function, current significant and the reform necessity.

从社会层级结构概念的基本规定、深层意蕴和性状表现三个方面界定社会层级结构概念,认为社会层级结构既是一种实体性存在和社会现实,也是一种观念性存在和理论构造,是物理空间和意义空间的统一;从政治哲学视野,社会层级结构是在政治国家内部按照权力至上的方式形成的权力级别或权力阶梯,并渗透到经济、文化、社会领域,形成具有普遍性的社会关系体系;它以总体社会结构为依托,以社会制度为外化,以政治权力为中轴;它既不是政治结构的翻版,不是社会阶层结构的别名,也不是经济、文化、社会结构的简单叠加,而是对它们层级性的一种抽象和概括;这种结构长期隐而不显,但却无处不在、无时不有,深深地影响和牢牢地控制着社会制度、人的生活和人的思维方式。

The vibration response of the viaduct structure by steel spring bearing, the viaduct structure by laminated rubber bearing, the track structure by Colon egg vibration damper, the track structure by steel spring damper and the ballast bed track structure are simulated through vehicle passed. The vibration parameter of the viaduct is optimized and the vibration transfer function characteristic of the ballast bed track structure and the track structure by steel spring damper are compared.

对钢弹簧支座高架桥结构、普通板式橡胶支座高架桥结构、克隆蛋减振器式轨道结构、钢弹簧浮置板减振器式轨道结构和普通碎石道床轨道结构在列车运行作用下的振动响应进行了仿真研究分析,对高架桥结构隔振参数进行了优化,比较了浮置板式和普通碎石道床轨道结构的振动传递特性。

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